DICP OpenIR
Coordination-induced CO2 fixation into carbonate by metal oxides
Zhao, Zhi1,2; Kong, Xiangtao1; Yuan, Qinqin1,3; Xie, Hua1; Yang, Dong1,3; Zhao, Jijun2; Fan, Hongjun1; Jiang, Ling1
Corresponding AuthorFan, Hongjun(fanhj@dicp.ac.cn) ; Jiang, Ling(ljiang@dicp.ac.cn)
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2018-08-07
ISSN1463-9076
DOI10.1039/c8cp02085j
Volume20Issue:29Pages:19314-19320
Funding ProjectNational Natural Science Foundation of China[21327901] ; National Natural Science Foundation of China[21503222] ; National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[11574040] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17000000]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordDRIVEN REDUCTIVE ACTIVATION ; INFRARED-SPECTROSCOPY ; SURFACE-CHEMISTRY ; ANIONIC COMPLEXES ; NEGATIVE CHARGE ; DIOXIDE ; CLUSTERS ; ION ; SOLVATION ; SPECTRA
AbstractHere, we have investigated how coordination induces CO2 fixation into a carbonate using a cationic yttrium oxide model catalyst. The infrared spectra show that the first three CO2 molecules are weakly bound to the metal. Subsequent coordination of CO2 ligands leads to the formation of a carbonate complex and results in a core ion transition. The conversion of Y = O and CO2 to carbonate is achieved by the donation of electrons from the ligands to the metal. Systematic analyses of the effects of different ligands and metals on the coordination-induced CO2 fixation demonstrate that the present system serves as an efficient and rational model for adjusting CO2 fixation and CO2 emission.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS IDWOS:000448132600003
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166807
Collection中国科学院大连化学物理研究所
Corresponding AuthorFan, Hongjun; Jiang, Ling
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Key Lab Mat Modificat Laser Ion & Electron Beams, Minist Educ, Dalian 116024, Peoples R China
3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Zhi,Kong, Xiangtao,Yuan, Qinqin,et al. Coordination-induced CO2 fixation into carbonate by metal oxides[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(29):19314-19320.
APA Zhao, Zhi.,Kong, Xiangtao.,Yuan, Qinqin.,Xie, Hua.,Yang, Dong.,...&Jiang, Ling.(2018).Coordination-induced CO2 fixation into carbonate by metal oxides.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(29),19314-19320.
MLA Zhao, Zhi,et al."Coordination-induced CO2 fixation into carbonate by metal oxides".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.29(2018):19314-19320.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhao, Zhi]'s Articles
[Kong, Xiangtao]'s Articles
[Yuan, Qinqin]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhao, Zhi]'s Articles
[Kong, Xiangtao]'s Articles
[Yuan, Qinqin]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhao, Zhi]'s Articles
[Kong, Xiangtao]'s Articles
[Yuan, Qinqin]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.