DICP OpenIR
Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids
Paridala, Kumaraswamy; Lu, Sheng-Mei; Wang, Meng-Meng; Li, Can
Corresponding AuthorLi, Can(canli@dicp.ac.cn)
Source PublicationCHEMICAL COMMUNICATIONS
2018-10-21
ISSN1359-7345
DOI10.1039/c8cc06820h
Volume54Issue:82Pages:11574-11577
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMETAL-CATALYZED CARBOXYLATION ; CARBON-DIOXIDE ; HYDROSILYLATION ; HYDROFORMYLATION ; TRANSFORMATION ; SURROGATES
AbstractThe present study discloses the synthesis of aryl/vinyl carboxylic acids from Csp(2)-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate. Hydrosilane provides hydride for reduction and its oxidation product silanol serves as a coupling partner. Mono-, di-, and tri-carboxylic acids were obtained from the corresponding aryl/vinyl halides.
Language英语
WOS IDWOS:000447181600013
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166861
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Can
AffiliationChinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Zhongshan Rd 457, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Paridala, Kumaraswamy,Lu, Sheng-Mei,Wang, Meng-Meng,et al. Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids[J]. CHEMICAL COMMUNICATIONS,2018,54(82):11574-11577.
APA Paridala, Kumaraswamy,Lu, Sheng-Mei,Wang, Meng-Meng,&Li, Can.(2018).Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids.CHEMICAL COMMUNICATIONS,54(82),11574-11577.
MLA Paridala, Kumaraswamy,et al."Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids".CHEMICAL COMMUNICATIONS 54.82(2018):11574-11577.
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