DICP OpenIR
Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control
Zhou, Xukai1,2; Sun, Jiaqiong1; Li, Xingwei1
Corresponding AuthorLi, Xingwei(xwli@dicp.ac.cn)
KeywordRh(III)-catalysis Chemo-selectivity Annulation Substrate control Condition control
Source PublicationCHINESE JOURNAL OF CATALYSIS
2018-11-01
ISSN0253-9837
DOI10.1016/S1872-2067(18)63134-1
Volume39Issue:11Pages:1782-1791
Funding ProjectNational Nature Science Foundation of China[21525208] ; National Nature Science Foundation of China[21472186] ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
Funding OrganizationNational Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordC-H ACTIVATION ; TRANSFER HYDROGENATION ; BOND ACTIVATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; DIRECT FUNCTIONALIZATION ; QUINOLIZIDINE ALKALOIDS ; NITROGEN-HETEROCYCLES ; ALCOHOL OXIDATION ; RHODIUM CATALYSIS ; DIRECTING GROUP
AbstractRh(III)-catalyzed C-H activation of N-protected anilines and chemo-divergent couplings with acroleins/enones have been realized for synthesis of three classes of heterocycles. The oxidative coupling of N-pyridylaniline afforded dihydroquinolones with the acrolein being a major hydrogen acceptor. When the directing group was replaced by pyrimidyl in the same system, redox-neutral coupling occurred to afford hemiaminal ethers. Oxidative annulation of N-pyridylanilines with enones using AgBF4 oxidant afforded atropisomeric quinolinium salts. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
Funding OrganizationNational Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
WOS IDWOS:000447958500008
PublisherSCIENCE PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166871
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Xingwei
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Xukai,Sun, Jiaqiong,Li, Xingwei. Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(11):1782-1791.
APA Zhou, Xukai,Sun, Jiaqiong,&Li, Xingwei.(2018).Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control.CHINESE JOURNAL OF CATALYSIS,39(11),1782-1791.
MLA Zhou, Xukai,et al."Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control".CHINESE JOURNAL OF CATALYSIS 39.11(2018):1782-1791.
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