DICP OpenIR
Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2
Li, Yanbang1; Lou, Ning1; Xu, Dan1; Pan, Changwang2; Lu, Xing2; Gan, Liangbing1,3
Corresponding AuthorLu, Xing(lux@hust.edu.cn) ; Gan, Liangbing(gan@pku.edu.cn)
Keywordencapsulation fullerenes hydrogen peroxide molecular containers open-cage fullerenes
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2018-10-22
ISSN1433-7851
DOI10.1002/anie.201808926
Volume57Issue:43Pages:14144-14148
Funding ProjectNNSFC[21132007] ; NNSFC[21672009] ; NNSFC[51472095] ; NNSFC[51672093] ; MOST[2015CB856600]
Funding OrganizationNNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMOLECULAR-HYDROGEN ; CARBON-ATOM ; C-60 ; CYANIDE
AbstractAn open-cage [60]fullerene was prepared through a multiple-step sequence based on peroxide-mediated cage-opening reactions. Key steps include repeated C-60-sensitized singlet-oxygen oxidation of electron-rich amino enol double bonds to form two lactone and two lactam moieties on the rim of the orifice. Single-crystal X-ray analysis shows that the 22-membered orifice has an ellipsoid shape with the major axis at 6.7 angstrom and the minor axis at 3.5 angstrom. Encapsulation of H2O2 was observed under atmospheric pressure at room temperature. Oxygen is also effectively trapped during the process.
Language英语
Funding OrganizationNNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST
WOS IDWOS:000447371500027
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166929
Collection中国科学院大连化学物理研究所
Corresponding AuthorLu, Xing; Gan, Liangbing
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China
3.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Li, Yanbang,Lou, Ning,Xu, Dan,et al. Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(43):14144-14148.
APA Li, Yanbang,Lou, Ning,Xu, Dan,Pan, Changwang,Lu, Xing,&Gan, Liangbing.(2018).Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(43),14144-14148.
MLA Li, Yanbang,et al."Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.43(2018):14144-14148.
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