DICP OpenIR
Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework
Guo, Peng1,2; Afeworki, Mobae3; Cao, Guang4; Yun, Yifeng1,5; Sun, Junliang1; Su, Jie1; Wan, Wei1; Zou, Xiaodong1
Corresponding AuthorCao, Guang(guang.cao@exxonmobil.com) ; Zou, Xiaodong(xzou@mmk.su.se)
Source PublicationINORGANIC CHEMISTRY
2018-09-17
ISSN0020-1669
DOI10.1021/acs.inorgchem.8b01890
Volume57Issue:18Pages:11753-11760
Funding ProjectSwedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR
Funding OrganizationSwedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
WOS KeywordROTATION ELECTRON-DIFFRACTION ; ALUMINOPHOSPHATE MOLECULAR-SIEVES ; EMBEDDED ISORETICULAR STRUCTURES ; CRYSTALLINE INORGANIC SOLIDS ; X-RAY-DIFFRACTION ; ORGANIC FRAMEWORK ; 8-RING CHANNELS ; PORE-SIZE ; ZEOLITES ; FAMILY
AbstractTwo-dimensional zeolitic materials have drawn increasing attention because of their structural diversity, high accessible surface areas, and potential as precursors to form novel three-dimensional (3D) structures. Here we report a new layered fluoroaluminophosphate, denoted as EMM-9 (ExxonMobil Material #9), synthesized in the same synthesis system as that for a previously reported 3D framework structure EMM-8 (framework-type code: SFO) using an F- medium and 4-(dimethylamino)pyridine (DMAP) as the organic structure-directing agent. The structure of EMM-9 was solved from rotation electron diffraction data and refined against synchrotron powder X-ray diffraction data. The fluoroaluminophosphate layer of EMM-9 is composed of sti composite building units. The DMAP cations are located between the layers. pi-pi interactions between the DMAP cations and hydrogen bonding between the DMAP cations and layers were identified. The layered EMM-9 structure is closely related to the 3D framework structure of EMM-8 and can be transformed to EMM-8 by calcination.
Language英语
Funding OrganizationSwedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR
WOS IDWOS:000445165400052
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167003
Collection中国科学院大连化学物理研究所
Corresponding AuthorCao, Guang; Zou, Xiaodong
Affiliation1.Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China
3.ExxonMobil Res & Engn Co, R&D Support Serv, 1545 Route 22 East, Annandale, NJ 08801 USA
4.ExxonMobil Res & Engn Co, Proc Technol Dept, 1545 Route 22 East, Annandale, NJ 08801 USA
5.Synfuels China Technol Co Ltd, Leyuan South St 2,1 Yanqi Econ Dev Zone C, Beijing 101407, Peoples R China
Recommended Citation
GB/T 7714
Guo, Peng,Afeworki, Mobae,Cao, Guang,et al. Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework[J]. INORGANIC CHEMISTRY,2018,57(18):11753-11760.
APA Guo, Peng.,Afeworki, Mobae.,Cao, Guang.,Yun, Yifeng.,Sun, Junliang.,...&Zou, Xiaodong.(2018).Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework.INORGANIC CHEMISTRY,57(18),11753-11760.
MLA Guo, Peng,et al."Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework".INORGANIC CHEMISTRY 57.18(2018):11753-11760.
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