DICP OpenIR
A nanosized metal-organic framework confined inside a functionalized mesoporous polymer: an efficient CO2 adsorbent with metal defects
Jiao, Chengli1,2; Majeed, Zeeshan1; Wang, Guang-Hui1; Jiang, Heqing1,2
Corresponding AuthorJiang, Heqing(jianghq@qibebt.ac.cn)
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
2018-09-21
ISSN2050-7488
DOI10.1039/c8ta05323e
Volume6Issue:35Pages:17220-17226
Funding ProjectNational Natural Science Foundation of China[21403267] ; National Natural Science Foundation of China[21650110459] ; Qingdao Applied Basic Research Project[17-1-1-75-jch] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA 21060400]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS KeywordCARBON-DIOXIDE ; ADSORPTION ; COMPOSITES ; SEPARATION ; MEMBRANES ; NITROGEN ; FACILE ; NANOPARTICLES ; RESISTANCE ; MECHANISM
AbstractHybrids with a nanosized metal-organic framework (MOF) confined within a mesoporous structure have attracted increasing attention owing to their enhanced mass transfer and novel applications. However, effective control of MOF crystal growth within pores and further understanding of the structure-property relationship are challenging. Herein, we report the confinement of a nanosized metal-organic framework CAU-1 into a functionalized mesoporous polymer via a combined impregnation and solvent vapor growth process. Carbonyl and hydroxyl groups over the wall of the mesoporous polymer well boost the nucleation and growth of CAU-1, leading to the formation of a nanosized MOF inside the mesoporous polymer. In contrast to bulk CAU-1, the nanosized CAU-1 within the hybrid exhibits significantly enhanced CO2 adsorption capacity at low pressure. As confirmed using the Al-27 MAS NMR characterization technique, the confined nanosized CAU-1 is rich in aluminium defects. The improved CO2 adsorption properties probably result from the favorable diffusion kinetics and the presence of metal defects as active binding sites.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Qingdao Applied Basic Research Project ; Qingdao Applied Basic Research Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences
WOS IDWOS:000445218000054
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167061
Collection中国科学院大连化学物理研究所
Corresponding AuthorJiang, Heqing
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Funct Membrane Mat & Membrane Tec, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Jiao, Chengli,Majeed, Zeeshan,Wang, Guang-Hui,et al. A nanosized metal-organic framework confined inside a functionalized mesoporous polymer: an efficient CO2 adsorbent with metal defects[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(35):17220-17226.
APA Jiao, Chengli,Majeed, Zeeshan,Wang, Guang-Hui,&Jiang, Heqing.(2018).A nanosized metal-organic framework confined inside a functionalized mesoporous polymer: an efficient CO2 adsorbent with metal defects.JOURNAL OF MATERIALS CHEMISTRY A,6(35),17220-17226.
MLA Jiao, Chengli,et al."A nanosized metal-organic framework confined inside a functionalized mesoporous polymer: an efficient CO2 adsorbent with metal defects".JOURNAL OF MATERIALS CHEMISTRY A 6.35(2018):17220-17226.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Jiao, Chengli]'s Articles
[Majeed, Zeeshan]'s Articles
[Wang, Guang-Hui]'s Articles
Baidu academic
Similar articles in Baidu academic
[Jiao, Chengli]'s Articles
[Majeed, Zeeshan]'s Articles
[Wang, Guang-Hui]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Jiao, Chengli]'s Articles
[Majeed, Zeeshan]'s Articles
[Wang, Guang-Hui]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.