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Hydrogen cold plasma for synthesizing Pd/C catalysts: the effect of support–metal ion interaction
LI,Zhuang1; ZHANG,Xiuling1; ZHANG,Yuzhuo2; DUAN,Dongzhi1; DI,Lanbo1
Keywordhydrogen cold plasma Pd/C support–metal ion interaction supported metal catalysts Coulomb interaction CO oxidation
Source PublicationPlasma Science and Technology
2017-11-28
ISSN1009-0630
DOI10.1088/2058-6272/aa7f27
Volume20Issue:1
AbstractAbstract It has been found that cold plasma is a facile and environmentally benign method for synthesizing supported metal catalysts, and great efforts have been devoted to enlarging its applications. However, little work has been done to disclose the influence mechanism, which is significant for controllable synthesis. In this work, hydrogen cold plasma was adopted to synthesize a palladium catalyst supported on activated carbon (Pd/C-P) using H2PdCl4 as a Pd precursor followed by calcination in hydrogen gas to remove the chlorine ions. The Pd/C-P catalyst was found to be made of larger Pd nanoparticles showing a decreased migration to the support outer surface than that prepared by the conventional thermal hydrogen reduction method (Pd/C-C). Meanwhile, the pore diameter of the activated carbon support is small (~4 nm). Therefore, Pd/C-P exhibits lower CO oxidation activity than Pd/C-C. It was proposed that the strong interaction between the activated carbon and PdCl 4 2 ? , and the enhanced metal–support interaction caused by hydrogen cold plasma reduction made it difficult for Pd nanoparticles to migrate to the support outer surface. The larger-sized Pd nanoparticles for Pd/C-P may be due to the Coulomb interaction resulting in the disturbance of the metal–support interaction. This work has important guiding significance for the controllable synthesis of supported metal catalysts by hydrogen cold plasma.
Language英语
WOS IDIOP:1009-0630-20-1-aa7f27
PublisherIOP Publishing
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Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167069
Collection中国科学院大连化学物理研究所
Affiliation1.College of Physical Science and Technology, Dalian University, Dalian 116622, People’s Republic of China
2.State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
Recommended Citation
GB/T 7714
LI,Zhuang,ZHANG,Xiuling,ZHANG,Yuzhuo,等. Hydrogen cold plasma for synthesizing Pd/C catalysts: the effect of support–metal ion interaction[J]. Plasma Science and Technology,2017,20(1).
APA LI,Zhuang,ZHANG,Xiuling,ZHANG,Yuzhuo,DUAN,Dongzhi,&DI,Lanbo.(2017).Hydrogen cold plasma for synthesizing Pd/C catalysts: the effect of support–metal ion interaction.Plasma Science and Technology,20(1).
MLA LI,Zhuang,et al."Hydrogen cold plasma for synthesizing Pd/C catalysts: the effect of support–metal ion interaction".Plasma Science and Technology 20.1(2017).
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