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Single-atom catalysis: Bridging the homo- and heterogeneous catalysis
Chen, Fang1; Jiang, Xunzhu1,2; Zhang, Leilei1; Lang, Rui1; Qiao, Botao1
KeywordSingle-atom Catalysis Heterogenization Of Homogeneous Catalysts Hydroformation Hydrosilylation Activation Of C-h Bonds
Source PublicationCHINESE JOURNAL OF CATALYSIS
2018-05-01
ISSN0253-9837
DOI10.1016/51872-2067(18)63047-5
Volume39Issue:5Pages:893-898
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordN-C CATALYST ; SELECTIVE OXIDATION ; HYDROFORMYLATION ; PERFORMANCE
AbstractSingle-atom catalysis, the catalysis by single-atom catalysts (SACs), has attracted considerable attention in recent years as a new frontier in the heterogeneous catalysis field. SACs have the advantages of both homogeneous catalysts (isolated active sites) and heterogeneous catalysts (stable and easy to separate), and are thus predicted to be able to bridge the homo- and heterogeneous catalysis. This prediction was first experimentally demonstrated in 2016. In this mini-review, we summarize the few homogeneous catalysis progresses reported recently where SACs have exhibited promising application: a) Rh/ZnO and Rh/CoO SAC have been used successfully in hydroformylation of olefin of which the activity are comparable to the homogeneous Wilkinson's catalyst; b) a Pt/Al2O3 SAC has shown excellent performance in hydrosilylation reaction; and c) M-N-C SACs (M = Fe, Co etc.) have been applied in the activation of C-H bonds. All of these examples suggest that fabrication of suitable SACs could provide a new avenue for the heterogenization of homogeneous catalysts. These pioneering works shed new light on the recognition of single-atom catalysis in bridging the homo- and heterogeneous catalysis. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000431834500001
PublisherSCIENCE PRESS
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Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167141
Collection中国科学院大连化学物理研究所
Corresponding AuthorQiao, Botao
Affiliation1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Dalian Univ Technol, Sch Chem, Dalian 116024, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Chen, Fang,Jiang, Xunzhu,Zhang, Leilei,et al. Single-atom catalysis: Bridging the homo- and heterogeneous catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(5):893-898.
APA Chen, Fang,Jiang, Xunzhu,Zhang, Leilei,Lang, Rui,&Qiao, Botao.(2018).Single-atom catalysis: Bridging the homo- and heterogeneous catalysis.CHINESE JOURNAL OF CATALYSIS,39(5),893-898.
MLA Chen, Fang,et al."Single-atom catalysis: Bridging the homo- and heterogeneous catalysis".CHINESE JOURNAL OF CATALYSIS 39.5(2018):893-898.
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