DICP OpenIR
Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor
Liu, Fei1; Liu, Qiaoyun1,2; Xu, Jinming1; Li, Lei3; Cui, Yi-Tao4; Lang, Rui1; Li, Lin1; Su, Yang1; Miao, Shu1; Sun, Hui1; Qiao, Botao1; Wang, Aiqin1; Jerome, Francois5; Zhang, Tao1
Source PublicationGREEN CHEMISTRY
2018-04-21
ISSN1463-9262
DOI10.1039/c8gc00039e
Volume20Issue:8Pages:1770-1776
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary ; GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY
WOS Research AreaChemistry ; Science & Technology - Other Topics
WOS KeywordLEVULINIC ACID ; GAMMA-VALEROLACTONE ; ETHYLENE-GLYCOL ; CHEMOSELECTIVE HYDROGENOLYSIS ; HYDROGENATION ; CHEMICALS ; BIOMASS ; OXIDATION ; CELLULOSE ; PLATFORM
AbstractThe synthesis of bio-based linear diols is the subject of many research studies. However, one of the main obstacles in industrial development is the difficulty in controlling product selectivity. Here, we report the catalytic conversion of furfural to 1,4-pentanediol (PD) in the presence of Ru supported on an ordered mesoporous carbon (CMK-3) under pressure of H-2 and CO2 in water. In contrast to previous catalytic pathways, this work is distinct in that it yields 1,4-PD as an exclusive product, instead of a mixture of 1,2-and 1,5-PD as usual. Under optimized conditions, 1,4-PD was obtained in 90% yield, and in a one-pot reaction, directly from furfural. We disclose that the conversion of furfural to 1,4-PD followed an unusual catalytic route. It implies a bifunctional catalytic pathway based on sequential catalytic hydrogenation reactions and an acid-catalyzed Piancatelli's rearrangement.
Language英语
WOS IDWOS:000430708900009
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167185
Collection中国科学院大连化学物理研究所
Corresponding AuthorQiao, Botao; Wang, Aiqin; Jerome, Francois
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Univ Hyogo, Synchrotron Radiat Nanotechnol Ctr, Kobe, Hyogo 6795165, Japan
4.Univ Tokyo, Inst Solid State Phys, Tokyo, Hyogo 6795198, Japan
5.Univ Poitiers, CNRS, Inst Chim Milieux & Mat Poitiers, F-86073 Poitiers, France
Recommended Citation
GB/T 7714
Liu, Fei,Liu, Qiaoyun,Xu, Jinming,et al. Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor[J]. GREEN CHEMISTRY,2018,20(8):1770-1776.
APA Liu, Fei.,Liu, Qiaoyun.,Xu, Jinming.,Li, Lei.,Cui, Yi-Tao.,...&Zhang, Tao.(2018).Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor.GREEN CHEMISTRY,20(8),1770-1776.
MLA Liu, Fei,et al."Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor".GREEN CHEMISTRY 20.8(2018):1770-1776.
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