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Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes
Li, Yanbang1; Gan, Liangbing1,2
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2014-09-19
ISSN0022-3263
DOI10.1021/jo5015867
Volume79Issue:18Pages:8912-8916
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordVIVO GENE DELIVERY ; ELECTRON-TRANSFER ; TERTIARY-AMINES ; FUNCTIONALIZED FULLERENES ; DERIVATIVES ; FACILE ; OXYGEN ; PHOTOADDITION ; PIPERAZINE ; OXIDANT
AbstractSecondary amines are well-known to add to [60]fullerene to form the tetraamino epoxy adduct C-60(O)(NR1R2)(4) under both photolysis and thermal conditions in the presence of oxygen. We have now found that pentaamino hydroxyl adduct C-60(OH)(NR1R2)(5) and hexaamino adduct C-60(NR1R2)(6) can be formed as the major products in the dark in the presence of oxygen. Key steps of the reaction mechanism probably involve repeated oxygen oxidation of the radical ion pair between fullerene and amines.
Language英语
WOS IDWOS:000342121100048
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167317
Collection中国科学院大连化学物理研究所
Corresponding AuthorGan, Liangbing
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Li, Yanbang,Gan, Liangbing. Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(18):8912-8916.
APA Li, Yanbang,&Gan, Liangbing.(2014).Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes.JOURNAL OF ORGANIC CHEMISTRY,79(18),8912-8916.
MLA Li, Yanbang,et al."Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes".JOURNAL OF ORGANIC CHEMISTRY 79.18(2014):8912-8916.
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