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Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane
Liang, Sisi1; Xu, Liang1; Jia, Zhenshan1; Gan, Liangbing1,2
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2014-06-20
ISSN0022-3263
DOI10.1021/jo5009228
Volume79Issue:12Pages:5794-5798
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordNUCLEOPHILIC-SUBSTITUTION ; VICINAL FULLERENDIOL ; FLUOROALKYL GROUP ; DERIVATIVES ; BUCKMINSTERFULLERENE ; OXIDATION ; TRIS(PENTAFLUOROPHENYL)BORON ; B(C6F5)(3) ; ALCOHOLS ; ETHERS
AbstractUnlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C-60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.
Language英语
WOS IDWOS:000337871100042
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/167361
Collection中国科学院大连化学物理研究所
Corresponding AuthorGan, Liangbing
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Liang, Sisi,Xu, Liang,Jia, Zhenshan,et al. Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(12):5794-5798.
APA Liang, Sisi,Xu, Liang,Jia, Zhenshan,&Gan, Liangbing.(2014).Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane.JOURNAL OF ORGANIC CHEMISTRY,79(12),5794-5798.
MLA Liang, Sisi,et al."Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane".JOURNAL OF ORGANIC CHEMISTRY 79.12(2014):5794-5798.
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