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Solid-State Photoinduced Luminescence Switch for Advanced Anticounterfeiting and Super-Resolution Imaging Applications
Qi, Qingkai1,2; Li, Chong3; Liu, Xiaogang4; Jiang, Shan1; Xu, Zhaochao2; Lee, Richmond4; Zhu, Mingqiang3; Xu, Bin1; Tian, Wenjing1
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2017-11-15
ISSN0002-7863
DOI10.1021/jacs.7b07738
Volume139Issue:45Pages:16036-16039
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMOLECULAR SWITCHES ; LIGHT ; SPIROPYRAN ; FLUORESCENCE ; NANOPARTICLES ; PHOTOCHROMISM ; PRODUCT ; PROTON ; SENSOR
AbstractSolid-state organic photoswitches with reversible luminescence modulation property are highly attractive because of their wide prospects in advanced photonic applications, such as optical data storage, anticounterfeiting and bioimaging. Yet, developing such materials has long been a significant challenge. In this work, we construct an efficient solid-state photoswitch based on a spiropyran-functionalized distyrylanthracene derivative (DSA-2SP) that exhibits exceptional reversible absorption/luminescence modulation ability. Efficient photoswitching between DSA-2SP and its photoisomer DSA-2MC are facilitated by large free volumes induced by nonplanar molecular structures of DSA moieties, as well as the intramolecular hydrogen bonds between the DSA and MC moieties. Consequently, the excellent solid-state photochromic property of DSA-2SP is highly applicable as both anticounterfeiting inks and super-resolution imaging agents.
Language英语
WOS IDWOS:000415785900004
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168357
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu, Bin
Affiliation1.Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Jilin, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Opt & Elect Informat, Wuhan 430074, Hubei, Peoples R China
4.Singapore Univ Technol & Design, 8 Somapah Rd, Singapore 487372, Singapore
Recommended Citation
GB/T 7714
Qi, Qingkai,Li, Chong,Liu, Xiaogang,et al. Solid-State Photoinduced Luminescence Switch for Advanced Anticounterfeiting and Super-Resolution Imaging Applications[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(45):16036-16039.
APA Qi, Qingkai.,Li, Chong.,Liu, Xiaogang.,Jiang, Shan.,Xu, Zhaochao.,...&Tian, Wenjing.(2017).Solid-State Photoinduced Luminescence Switch for Advanced Anticounterfeiting and Super-Resolution Imaging Applications.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(45),16036-16039.
MLA Qi, Qingkai,et al."Solid-State Photoinduced Luminescence Switch for Advanced Anticounterfeiting and Super-Resolution Imaging Applications".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.45(2017):16036-16039.
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