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Unique Transformation from Graphene to Carbide on Re(0001) Induced by Strong Carbon-Metal Interaction
Qi, Yue1; Meng, Caixia2; Xu, Xiaozhi3; Deng, Bing1; Han, Nannan4; Liu, Mengxi5; Hong, Min6; Ning, Yanxiao2; Liu, Kaihui3; Zhao, Jijun4; Fu, Qiang2; Li, Yuanchang7; Zhang, Yanfeng1,6,8; Liu, Zhongfan1,8
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2017-12-06
ISSN0002-7863
DOI10.1021/jacs.7b09755
Volume139Issue:48Pages:17574-17581
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCHEMICAL-VAPOR-DEPOSITION ; HIGH-QUALITY ; GROWTH ; FILMS ; REACTIVITIES ; NITRIDE ; SURFACE
AbstractDuring graphene growth on various transition metals in the periodic table, metal carbides always emerge to behave as complex intermediates. On VIII metals, metastable carbides usually evolve and then transform into graphene along the phase interfaces, and even no metal carbides can form on IB-IIB metals. In contrast, during graphene growth on group IVB-VIB metals, carbides are usually generated even before the evolution of graphene and stably exist throughout the whole growth process. However, for the remaining transition metals, e.g., group VIIB, located in between IVB-VIB and VIII, the interplay between graphene and carbide is still vague. Herein, on Re(0001) (VIIB), we have revealed a novel transition from graphene to metal carbide (reverse to that on VIII metals) for the first time. This transition experienced graphene decomposition, dissolution, and carbon segregation processes, as evidenced by scanning tunneling microscopy (STM) and on-site, variable-temperature low electron energy diffraction (LEED) characterizations. This work thus completes the picture about the interplay between graphene and carbide on/in transition metals in the periodic table, as well as discloses a new territory for the growth of carbon-related materials, especially the metal carbide.
Language英语
WOS IDWOS:000417669000054
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168393
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Yuanchang; Zhang, Yanfeng; Liu, Zhongfan
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Acad Adv Interdisciplinary Studies, Coll Chem & Mol Engn,Ctr Nanochem CNC, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Peking Univ, Acad Adv Interdisciplinary Studies, Sch Phys, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China
4.Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116024, Peoples R China
5.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
6.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China
7.Beijing Inst Technol, Adv Res Inst Multidisciplinary Sci, Beijing 100081, Peoples R China
8.BGI, Beijing 100095, Peoples R China
Recommended Citation
GB/T 7714
Qi, Yue,Meng, Caixia,Xu, Xiaozhi,et al. Unique Transformation from Graphene to Carbide on Re(0001) Induced by Strong Carbon-Metal Interaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(48):17574-17581.
APA Qi, Yue.,Meng, Caixia.,Xu, Xiaozhi.,Deng, Bing.,Han, Nannan.,...&Liu, Zhongfan.(2017).Unique Transformation from Graphene to Carbide on Re(0001) Induced by Strong Carbon-Metal Interaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(48),17574-17581.
MLA Qi, Yue,et al."Unique Transformation from Graphene to Carbide on Re(0001) Induced by Strong Carbon-Metal Interaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.48(2017):17574-17581.
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