DICP OpenIR
Ru(II)-Catalyzed Cross-Coupling of Cyclopropenes with Diazo Compounds: Formation of Olefins from Two Different Carbene Precursors
Wang, Bo1; Yi, Heng1; Zhang, Hang1; Sun, Tong1; Zhang, Yan1; Wang, Jianbo1,2
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2018-01-19
ISSN0022-3263
DOI10.1021/acs.joc.7b02634
Volume83Issue:2Pages:1026-1032
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordCATALYZED SYNTHESIS ; EFFICIENT APPROACH ; ALKENE FORMATION ; CYCLIZATION ; COMPLEXES ; METAL ; MACROCYCLIZATION ; REARRANGEMENT ; DIAZOKETONES ; DERIVATIVES
AbstractFormal carbene dimerization is a convergent method for the synthesis of alkenes. Herein, we report a Ru(II)-catalyzed carbene dimerization of cyclopropenes and diazo compounds. The yields are up to 97% and the stereoselectivity are up to >20:1. Mechanistically, it has been experimentally demonstrated that the catalyst reacts with cyclopropene first to generate a Ru(II) carbene species, which is attacked by nucleophilic diazo substrate, followed by dinitrogen extrusion to form the double bond.
Language英语
WOS IDWOS:000423252300047
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168661
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Jianbo
Affiliation1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Wang, Bo,Yi, Heng,Zhang, Hang,et al. Ru(II)-Catalyzed Cross-Coupling of Cyclopropenes with Diazo Compounds: Formation of Olefins from Two Different Carbene Precursors[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(2):1026-1032.
APA Wang, Bo,Yi, Heng,Zhang, Hang,Sun, Tong,Zhang, Yan,&Wang, Jianbo.(2018).Ru(II)-Catalyzed Cross-Coupling of Cyclopropenes with Diazo Compounds: Formation of Olefins from Two Different Carbene Precursors.JOURNAL OF ORGANIC CHEMISTRY,83(2),1026-1032.
MLA Wang, Bo,et al."Ru(II)-Catalyzed Cross-Coupling of Cyclopropenes with Diazo Compounds: Formation of Olefins from Two Different Carbene Precursors".JOURNAL OF ORGANIC CHEMISTRY 83.2(2018):1026-1032.
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