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Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism
Gupta, Neeraj1,2; Khavryuchenko, Oleksiy3,4; Wen, Guodong1; Wu, Kuang-Hsu1; Su, Dangsheng1,5
Source PublicationCARBON
2018-04-01
ISSN0008-6223
DOI10.1016/j.carbon.2018.01.045
Volume130Pages:714-723
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Materials Science
WOS KeywordMETAL-FREE CATALYST ; CARBON NANOTUBES ; OXIDATIVE DEHYDROGENATION ; GRAPHENE OXIDE ; HYDRAZINE ; EFFICIENT ; NANODIAMONDS ; EXCHANGE ; GLYCEROL ; BENZENE
AbstractCarbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000424889200084
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168675
Collection中国科学院大连化学物理研究所
Corresponding AuthorSu, Dangsheng
Affiliation1.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
2.Shoolini Univ, Sch Chem, Fac Basic Sci, Solan 173229, HP, India
3.TMM LLC, Res & Dev Dept, Volodymyrska Str 49a, UA-01601 Kiev, Ukraine
4.Ctr Res Mol Modeling, Montreal, PQ H4B 1R6, Canada
5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Gupta, Neeraj,Khavryuchenko, Oleksiy,Wen, Guodong,et al. Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism[J]. CARBON,2018,130:714-723.
APA Gupta, Neeraj,Khavryuchenko, Oleksiy,Wen, Guodong,Wu, Kuang-Hsu,&Su, Dangsheng.(2018).Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism.CARBON,130,714-723.
MLA Gupta, Neeraj,et al."Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism".CARBON 130(2018):714-723.
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