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Chiral Ag-23 nanocluster with open shell electronic structure and helical face-centered cubic framework
Liu, Chao1; Li, Tao2; Abroshan, Hadi3; Li, Zhimin1; Zhang, Chen4; Kim, Hyung J.3,5; Li, Gao1; Jin, Rongchao3
Source PublicationNATURE COMMUNICATIONS
2018-02-21
ISSN2041-1723
DOI10.1038/s41467-018-03136-9
Volume9
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordSILVER NANOPARTICLES ; OPTICAL-PROPERTIES ; CIRCULAR-DICHROISM ; CRYSTAL-STRUCTURES ; GOLD CLUSTERS ; THIOLATE ; EXCHANGE ; DENSITY ; METAL ; POTENTIALS
AbstractWe report the synthesis and crystal structure of a nanocluster composed of 23 silver atoms capped by 8 phosphine and 18 phenylethanethiolate ligands. X-ray crystallographic analysis reveals that the kernel of the Ag nanocluster adopts a helical face-centered cubic structure with C-2 symmetry. The thiolate ligands show two binding patterns with the surface Ag atoms: tri- and tetra-podal types. The tetra-coordination mode of thiolate has not been found in previous Ag nanoclusters. No counter ion (e.g., Na+ and NO3-) is found in the single-crystal and the absence of such ions is also confirmed by X-ray photoelectron spectroscopy analysis, indicating electrical neutrality of the nanocluster. Interestingly, the nanocluster has an open shell electronic structure (i.e., 23(Ag 5s(1))-18(SR) = 5e), as confirmed by electron paramagnetic resonance spectroscopy. Time-dependent density functional theory calculations are performed to correlate the structure and optical absorption/emission spectra of the Ag nanocluster.
Language英语
WOS IDWOS:000425594200004
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168815
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Gao; Jin, Rongchao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
4.Univ Missouri, Dept Chem, Columbia, MO 65211 USA
5.Korea Inst Adv Study, Sch Computat Sci, Seoul 02455, South Korea
Recommended Citation
GB/T 7714
Liu, Chao,Li, Tao,Abroshan, Hadi,et al. Chiral Ag-23 nanocluster with open shell electronic structure and helical face-centered cubic framework[J]. NATURE COMMUNICATIONS,2018,9.
APA Liu, Chao.,Li, Tao.,Abroshan, Hadi.,Li, Zhimin.,Zhang, Chen.,...&Jin, Rongchao.(2018).Chiral Ag-23 nanocluster with open shell electronic structure and helical face-centered cubic framework.NATURE COMMUNICATIONS,9.
MLA Liu, Chao,et al."Chiral Ag-23 nanocluster with open shell electronic structure and helical face-centered cubic framework".NATURE COMMUNICATIONS 9(2018).
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