DICP OpenIR
Versatile design and synthesis of mesoporous sulfonic acid catalysts
Wang, Peng1,2; Zhao, Yupei1,2; Liu, Jian3,4
KeywordMesoporous Materials Sulfonic Acid Catalysts Nanoreactors Microenvironment Biomass Conversion
Source PublicationSCIENCE BULLETIN
2018-02-28
ISSN2095-9273
DOI10.1016/j.scib.2018.01.017
Volume63Issue:4Pages:252-266
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordHIGHLY SELECTIVE CATALYST ; CELLULOSE-DERIVED CARBON ; METAL-ORGANIC FRAMEWORKS ; SOLID ACID ; HETEROGENEOUS CATALYSTS ; LEVULINIC ACID ; IONIC LIQUIDS ; GREEN CHEMISTRY ; GRAPHENE OXIDE ; BIODIESEL SYNTHESIS
AbstractMesoporous sulfonic acid catalysts (MSAC) are widely used in acid-catalyzed reactions, including bio-mass conversions with plenty of polar solvents and precursors. The catalytic efficiency of MSAC is greatly affected by the microenvironment around the sulfonic acid sites. In this review, the progress on modification of microenvironment of MSAC is reviewed over the past decade. Hydrophobic modification allows MSAC prevent the adhesion of water molecules onto sulfonic acid sites, to abate the risk of reduced acid strength and catalytic efficiency. In comparison, hydrophilic properties can bring positive effect on acid-catalyzed reactions with the aid of hydrophilic interaction between polar functional groups on MSAC and hydrophilic groups of specific substrates. Amphiphilic MSAC with tunable wettability for specific substrates and solvents tend to improve the efficiency in certain reactions with mixed solvents or reactants of different polarity, especially for biphasic systems of immiscible liquids. Furthermore, much attention has been attracted on modification of surface to simulate the microenvironment of homogeneous solvents and enzyme biocatalysts in recent research. New trends of this field are also highlighted. (C) 2018 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
Language英语
WOS IDWOS:000425946900010
PublisherSCIENCE PRESS
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168819
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Peng; Liu, Jian
Affiliation1.Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
2.Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Changzhou 213164, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, Dalian 116023, Peoples R China
4.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England
Recommended Citation
GB/T 7714
Wang, Peng,Zhao, Yupei,Liu, Jian. Versatile design and synthesis of mesoporous sulfonic acid catalysts[J]. SCIENCE BULLETIN,2018,63(4):252-266.
APA Wang, Peng,Zhao, Yupei,&Liu, Jian.(2018).Versatile design and synthesis of mesoporous sulfonic acid catalysts.SCIENCE BULLETIN,63(4),252-266.
MLA Wang, Peng,et al."Versatile design and synthesis of mesoporous sulfonic acid catalysts".SCIENCE BULLETIN 63.4(2018):252-266.
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