DICP OpenIR
Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5-
Wang, Li-Na1,3,4; Li, Xiao-Na1,4; Jiang, Li-Xue1,3,4; Yang, Bin2,3,4; Liu, Qing-Yu1,4; Xu, Hong-Guang2,4; Zheng, Wei-Jun2,4; He, Sheng-Gui1,3,4
KeywordCarbon Monoxide Copper Heterogeneous Catalysis Mass Spectrometry Vanadium
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2018-03-19
ISSN1433-7851
DOI10.1002/anie.201712129
Volume57Issue:13Pages:3349-3353
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordALUMINUM-OXIDE CLUSTERS ; SINGLE-ATOM CATALYSIS ; GAS-PHASE ; GOLD CLUSTERS ; MOLECULAR-OXYGEN ; CARBON-MONOXIDE ; PLATINUM CLUSTERS ; N2O ; CATIONS ; ACTIVATION
AbstractCatalytic CO oxidation by molecular O-2 is an important model reaction in both the condensed phase and gas-phase studies. Available gas-phase studies indicate that noble metal is indispensable in catalytic CO oxidation by O-2 under thermal collision conditions. Herein, we identified the first example of noble-metal-free heteronuclear oxide cluster catalysts, the copper-vanadium bimetallic oxide clusters Cu2VO3-5- for CO oxidation by O-2. The reactions were characterized by mass spectrometry, photoelectron spectroscopy, and density functional calculations. The dynamic nature of the Cu-Cu unit in terms of the electron storage and release is the driving force to promote CO oxidation and O-2 activation during the catalysis.
Language英语
WOS IDWOS:000427235600010
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168907
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Xiao-Na; Zheng, Wei-Jun; He, Sheng-Gui
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Li-Na,Li, Xiao-Na,Jiang, Li-Xue,et al. Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5-[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(13):3349-3353.
APA Wang, Li-Na.,Li, Xiao-Na.,Jiang, Li-Xue.,Yang, Bin.,Liu, Qing-Yu.,...&He, Sheng-Gui.(2018).Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(13),3349-3353.
MLA Wang, Li-Na,et al."Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.13(2018):3349-3353.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Li-Na]'s Articles
[Li, Xiao-Na]'s Articles
[Jiang, Li-Xue]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Li-Na]'s Articles
[Li, Xiao-Na]'s Articles
[Jiang, Li-Xue]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Li-Na]'s Articles
[Li, Xiao-Na]'s Articles
[Jiang, Li-Xue]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.