DICP OpenIR
All-MXene-Based Integrated Electrode Constructed by Ti3C2 Nanoribbon Framework Host and Nanosheet Interlayer for High-Energy-Density Li-S Batteries
Dong, Yanfeng1; Zheng, Shuanghao1,3; Qin, Jieqiong1,3; Zhao, Xuejun1; Shi, Haodong1,3; Wang, Xiaohui2; Chen, Jian1; Wu, Zhong-Shuai1
KeywordMxene Nanosheets Integrated Electrode Flexible Lithium-sulfur Batteries
Source PublicationACS NANO
2018-03-01
ISSN1936-0851
DOI10.1021/acsnano.7b07672
Volume12Issue:3Pages:2381-2388
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS KeywordLITHIUM-SULFUR BATTERIES ; NITROGEN-DOPED GRAPHENE ; LONG-LIFE ; POLYSULFIDE MEDIATOR ; PERFORMANCE ; CATHODES ; PROGRESS ; OXIDE ; SEPARATOR ; ULTRAFAST
AbstractHigh-energy-density lithium-sulfur (Li-S) batteries hold promise for next-generation portable electronic devices, but are facing great challenges in rational construction of high-performance flexible electrodes and innovative cell configurations for actual applications. Here we demonstrated an all-MXene-based flexible and integrated sulfur cathode, enabled by three-dimensional alkalized Ti3C2 MXene nanoribbon (a-Ti3C2 MNR) frameworks as a S/polysulfides host (a-Ti3C2-S) and two-dimensional delaminated Ti3C2 MXene (d-Ti3C2) nano-sheets as interlayer on a polypropylene (PP) separator, for high-energy and long-cycle Li-S batteries. Notably, an a-Ti3C2 MNR framework with open interconnected macropores and an exposed surface area guarantees high S loading and fast ionic diffusion for prompt lithiation/delithiation kinetics, and the 2D d-Ti3C2 MXene interlayer remarkably prevents the shuttle effect of lithium polysulfides via both chemical absorption and physical blocking. As a result, the integrated a-Ti3C2-S/d-Ti3C2/PP electrode was directly used for Li-S batteries, without the requirement of a metal current collector, and exhibited a high reversible capacity of 1062 mAh g(-1) at 0.2 C and enhanced capacity of 632 mAh g(-1) after 50 cycles at 0.5 C, outperforming the a-Ti3C2-S/PP electrode (547 mAh g(-1)) and conventional a-Ti3C2-S on an Al current collector (a-Ti3C2-S/Al) (597 mAh g(-1)). Furthermore, the all-MXene-based integrated cathode displayed outstanding rate capacity of 288 mAh g(-1) at 10 C and long-life cyclability. Therefore, this proposed strategy of constructing an all-MXene-based cathode can be readily extended to assemble a large number of MXene-derived materials, from a group of 60+ MAX phases, for applications such as various batteries and supercapacitors.
Language英语
WOS IDWOS:000428972600030
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/168983
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Xiaohui; Wu, Zhong-Shuai
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Dong, Yanfeng,Zheng, Shuanghao,Qin, Jieqiong,et al. All-MXene-Based Integrated Electrode Constructed by Ti3C2 Nanoribbon Framework Host and Nanosheet Interlayer for High-Energy-Density Li-S Batteries[J]. ACS NANO,2018,12(3):2381-2388.
APA Dong, Yanfeng.,Zheng, Shuanghao.,Qin, Jieqiong.,Zhao, Xuejun.,Shi, Haodong.,...&Wu, Zhong-Shuai.(2018).All-MXene-Based Integrated Electrode Constructed by Ti3C2 Nanoribbon Framework Host and Nanosheet Interlayer for High-Energy-Density Li-S Batteries.ACS NANO,12(3),2381-2388.
MLA Dong, Yanfeng,et al."All-MXene-Based Integrated Electrode Constructed by Ti3C2 Nanoribbon Framework Host and Nanosheet Interlayer for High-Energy-Density Li-S Batteries".ACS NANO 12.3(2018):2381-2388.
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