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Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)
Xie, Hua1; Zou, Jinghan1,2; Yuan, Qinqin1,2; Zhang, Jumei1,2; Fan, Hongjun1; Jiang, Ling1
KeywordPhotoelectron Spectroscopy Co Activation Heteronuclear Metal Carbonyl Quantum Chemical Calculation
Source PublicationTOPICS IN CATALYSIS
2018-03-01
ISSN1022-5528
DOI10.1007/s11244-017-0875-0
Volume61Issue:1-2Pages:71-80
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordINFRARED PHOTODISSOCIATION SPECTROSCOPY ; DENSITY-FUNCTIONAL CALCULATIONS ; GAS-PHASE ; CLUSTER CATIONS ; COPPER CARBONYLS ; SOLID ARGON ; SPECTRA ; ATOMS ; MONOXIDE ; ANIONS
AbstractThe chemical bonding and electronic structure of heteronuclear metal-nickel carbonyls MNi(CO)(n)(-) (M = Sc, Y; n = 2-6) have been investigated by mass-selected photoelectron velocity map imaging spectroscopy and quantum chemical calculations. Two CO bonding modes (side-on-bonded and terminal carbonyls) are involved in the n = 2 cluster. The building block composed of three kinds of different CO modes (side-on-bonded, bridging, and terminal carbonyls) is favored at n = 3, the structure of which persists up to n = 6. The additional CO ligands are preferentially coordinated in the terminal mode to the Sc atom and then to the Ni atom in the larger clusters. The present findings would promote the understanding of CO molecule activation and chemisorbed CO molecules on metal surfaces.
Language英语
WOS IDWOS:000428065700009
PublisherSPRINGER/PLENUM PUBLISHERS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169069
Collection中国科学院大连化学物理研究所
Corresponding AuthorJiang, Ling
Affiliation1.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy & Mat iChEM, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xie, Hua,Zou, Jinghan,Yuan, Qinqin,et al. Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)[J]. TOPICS IN CATALYSIS,2018,61(1-2):71-80.
APA Xie, Hua,Zou, Jinghan,Yuan, Qinqin,Zhang, Jumei,Fan, Hongjun,&Jiang, Ling.(2018).Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6).TOPICS IN CATALYSIS,61(1-2),71-80.
MLA Xie, Hua,et al."Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)".TOPICS IN CATALYSIS 61.1-2(2018):71-80.
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