DICP OpenIR
A green route for methanol carbonylation
Ni, Youming1,2; Shi, Lei1,2; Liu, Hongchao1,2; Zhang, Wenna1,2,3; Liu, Yong1,2; Zhu, Wenliang1,2; Liu, Zhongmin1,2
Source PublicationCATALYSIS SCIENCE & TECHNOLOGY
2017-10-21
ISSN2044-4753
DOI10.1039/c7cy01621b
Volume7Issue:20Pages:4818-4822
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordDIMETHYL ETHER CARBONYLATION ; SOLID ACID CATALYSTS ; METHYL ACETATE ; SELECTIVE CARBONYLATION ; MORDENITE ZEOLITE ; SPECIFICITY ; PROMOTION ; MECHANISM ; CHANNELS ; SITES
AbstractAcetic acid is one of the most important bulk commodity chemicals and is currently manufactured by methanol carbonylation reactions with rhodium or iridium organometallic complexes and halide-containing promoters named Monsanto or BP Cativa T homogeneous processes, respectively. Developing a halide-free catalyst and a heterogeneous process for methanol carbonylation is of great importance and has recently attracted extensive research attention. Here, we report a green route for direct synthesis of acetic acid via vapor-phase carbonylation of methanol with a stable, selective, halide-free, and noble metal-free catalyst based on pyridine-modified H-mordenite zeolite. Methanol conversion and acetic acid selectivity can reach up to 100% and 95%, respectively. Only little deactivation is observed during the 145 hour reaction.
Language英语
WOS IDWOS:000413192900023
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169221
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhu, Wenliang; Liu, Zhongmin
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, PR, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ni, Youming,Shi, Lei,Liu, Hongchao,et al. A green route for methanol carbonylation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(20):4818-4822.
APA Ni, Youming.,Shi, Lei.,Liu, Hongchao.,Zhang, Wenna.,Liu, Yong.,...&Liu, Zhongmin.(2017).A green route for methanol carbonylation.CATALYSIS SCIENCE & TECHNOLOGY,7(20),4818-4822.
MLA Ni, Youming,et al."A green route for methanol carbonylation".CATALYSIS SCIENCE & TECHNOLOGY 7.20(2017):4818-4822.
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