DICP OpenIR
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx
Zhao, Xiaochen1; Wang, Jia1,3; Yang, Man1,2; Lei, Nian1,2; Li, Lin1; Hou, Baolin1; Miao, Shu1; Pan, Xiaoli1; Wang, Aiqin1; Zhang, Tao1
KeywordAu Promotion Frustrated Lewism Pairs Glycerol Hydrogenolysis 1 3-propanediol
Source PublicationCHEMSUSCHEM
2017-03-09
ISSN1864-5631
DOI10.1002/cssc.201601503
Volume10Issue:5Pages:819-824
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordIR-RE CATALYSTS ; CHEMOSELECTIVE HYDROGENATION ; BIMETALLIC CATALYSTS ; TUNGSTEN-OXIDE ; CHEMICALS ; HYDRODEOXYGENATION ; TEMPERATURE ; ACTIVATION ; CONVERSION ; SURFACES
AbstractA highly dispersed Au and Pt catalyst supported on WOx was developed for high performance in the selective hydrogenolysis of glycerol to 1,3-propanediol (1,3-PD) under very mild reaction conditions (81.4% glycerol conversion, 51.6% 1,3-PD selectivity at 413 K, 1 MPa H-2). The highly dispersed Au decreased the original surface Lewis-acid sites on Pt/WOx but greatly increased its in situ generated Bronsted-acid sites with the assistance of H2 through the formation of frustrated Lewis pairs. These in situ formed and spatially separated pairs of H+ and H+ function as the active sites in glycerol conversion to 1,3-PD.
Language英语
WOS IDWOS:000398182300001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169471
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Aiqin; Zhang, Tao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Northwest A&F Univ, Coll Forestry, 3 Taicheng Rd, Yangling 712100, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Xiaochen,Wang, Jia,Yang, Man,et al. Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx[J]. CHEMSUSCHEM,2017,10(5):819-824.
APA Zhao, Xiaochen.,Wang, Jia.,Yang, Man.,Lei, Nian.,Li, Lin.,...&Zhang, Tao.(2017).Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx.CHEMSUSCHEM,10(5),819-824.
MLA Zhao, Xiaochen,et al."Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx".CHEMSUSCHEM 10.5(2017):819-824.
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