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Cu2O Mediated Synthesis of Metal Organic Framework UiO-66 in Nanometer Scale
Han, Yitong1; Liu, Min1; Li, Keyan1; Sun, Qiao1; Song, Chunshan1,2,3; Zhang, Guoliang4; Zhang, Zongchao5; Guo, Xinwen1
Source PublicationCRYSTAL GROWTH & DESIGN
2017-02-01
ISSN1528-7483
DOI10.1021/acs.cgd.6b01533
Volume17Issue:2Pages:685-692
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Crystallography ; Materials Science
WOS KeywordGAS-ADSORPTION ; STABILITY ; MOF ; COORDINATION ; DEFECTS ; NANOPARTICLES ; CO2 ; CRYSTALLIZATION ; CATALYSIS ; MEMBRANES
AbstractControlled synthesis of metal organic frameworks (MOFs) in nanometer scale is highly desired for the optimization of properties and the extending of applications. In this work, Cu2O was used as additive for the first time in the synthesis of zirconium-based MOF UiO-66. We found that the amount of Cu2O additive had an important impact on downsizing the crystal size of UiO-66. Cu2O additive plays a role of rate controller of crystal growth of UiO-66 crystals by their competitive coordination behavior with the linker H2BDC between the [Zr-O] clusters. This generates a depleted H2BDC concentration for the coordination with the [Zr-O] clusters for constructing the UiO-66 framework, which favors the production of small crystals. As a result, well-dispersed nanometer scale UiO-66 crystals with mean crystal size of 40 nm can be easily synthesized by the addition of Cu2O. The as-synthesized nanometer scale UiO-66 crystals have a pure crystal structure with high crystallinity and superior porosity.
Language英语
WOS IDWOS:000393354100032
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169701
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Zongchao; Guo, Xinwen
Affiliation1.Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China
2.Penn State Univ, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA
3.Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA
4.Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou 310014, Zhejiang, Peoples R China
5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Han, Yitong,Liu, Min,Li, Keyan,et al. Cu2O Mediated Synthesis of Metal Organic Framework UiO-66 in Nanometer Scale[J]. CRYSTAL GROWTH & DESIGN,2017,17(2):685-692.
APA Han, Yitong.,Liu, Min.,Li, Keyan.,Sun, Qiao.,Song, Chunshan.,...&Guo, Xinwen.(2017).Cu2O Mediated Synthesis of Metal Organic Framework UiO-66 in Nanometer Scale.CRYSTAL GROWTH & DESIGN,17(2),685-692.
MLA Han, Yitong,et al."Cu2O Mediated Synthesis of Metal Organic Framework UiO-66 in Nanometer Scale".CRYSTAL GROWTH & DESIGN 17.2(2017):685-692.
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