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Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers
Chen, Qin1; Du, Jie-hao1; Xie, Hai-bo1; Zhao, Zong-bao2; Zheng, Qiang1
KeywordCatalytic Biorefinery Bio-based Monomers Bio-based Polymers Thermal Properties Mechanical Properties
Source PublicationACTA POLYMERICA SINICA
2016-10-20
ISSN1000-3304
DOI10.11777/j.issn1000-3304.2016.16154
Issue10Pages:1330-1358
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPolymer Science
WOS Research AreaPolymer Science
WOS KeywordRENEWABLE RESOURCES ; AEROBIC OXIDATION ; FERULIC ACID ; GAMMA-BUTYROLACTONE ; ITACONIC ACID ; POLY(FERULIC ACID-CO-TYROSINE) ; THERMOSETTING RESINS ; EPSILON-CAPROLACTONE ; POLYESTERS SYNTHESIS ; DELTA-VALEROLACTONE
AbstractThe search for sustainable resource for polymers production have been obtained much attentions due to the over exploration of fossil resources and environment problems arisen from the use of petroleum based polymeric materials. The modern biorefinery produced a spectrum of biobased chemicals, which can be further upgraded into polymeric monomers for polymer synthesis. This review summarized the latest progress in the synthesis of biobased polymeric monomers from renewable resources such as carbohydrates, lignocellulose and plan oils. According to their structure, those biobased polymeric monomers can be categorised into aliphatic monomers and aromatic monomers including acids, diols, furyl and vanillic monomers. Various strategies, such as catalytic process and fementaion process, were compared in terms of selectivity, yield and feasibility of target biobased monomers. Those biobased monomers can be directly employed as feedstock to prepare biobased polymers, such as polyesters, polyamides, polycarbonates, polyurethanes and polyethers. Besides, both the traditional and novel polymerization processes can be adopted to prepare biobased polymers, such as catalyst free melt condensation, radical polymerization, photocuring process, proton transfer polymerization and enzymatic polycondensations. The influence of various heating methods, catalyst loading, mole ratio, reaction time and temperature to prepare biobased polymers were compared. Those biobased polymers exhibit excellent mechanical and thermal properties and promising properties such as shape memory effect, self-healing properties and bacteria clearing effect, which revealed great potential to replace the petroleum based polymers. Finally, the future development of bio-based polymers has also discussed.
Language英语
WOS IDWOS:000387628200005
PublisherSCIENCE PRESS
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169717
Collection中国科学院大连化学物理研究所
Corresponding AuthorXie, Hai-bo
Affiliation1.Guizhou Univ, Coll Mat & Met, Dept Polymer Mat & Engn, Guiyang 550025, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Chen, Qin,Du, Jie-hao,Xie, Hai-bo,et al. Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers[J]. ACTA POLYMERICA SINICA,2016(10):1330-1358.
APA Chen, Qin,Du, Jie-hao,Xie, Hai-bo,Zhao, Zong-bao,&Zheng, Qiang.(2016).Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers.ACTA POLYMERICA SINICA(10),1330-1358.
MLA Chen, Qin,et al."Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers".ACTA POLYMERICA SINICA .10(2016):1330-1358.
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