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A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties
Jiao, Chengli1; Jiang, Xia2; Chu, Hailiang3; Jiang, Heqing1; Sun, Lixian3
Source PublicationCRYSTENGCOMM
2016
ISSN1466-8033
DOI10.1039/c6ce01827k
Volume18Issue:44Pages:8683-8687
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary ; Crystallography
WOS Research AreaChemistry ; Crystallography
WOS KeywordCOORDINATION POLYMER ; SOLVENT MOLECULES ; LIGAND ; LUMINESCENCE ; COMPLEXES ; CATALYSTS ; SORPTION ; SENSORS ; BINDING ; METHANE
AbstractA novel 3D mixed-valent Cu-I/Cu-II metal-organic framework has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, photoluminescence spectroscopy, thermal gravimetric analysis, and powder X-ray diffraction. The structure possesses a 3D open framework constructed from the linkages of 1D [Cu-I(4,4'-bipy)](n) chains with [Cu-II(oda)(2)](2-) cationic subunits. The chemical sensing properties of this MOF have been studied by the quartz crystal microbalance technique. The framework exhibits good selectivity and sensitivity to water with respect to other organic solvents in view of chemical sensing applications.
Language英语
WOS IDWOS:000387975900018
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169731
Collection中国科学院大连化学物理研究所
Corresponding AuthorJiang, Heqing; Sun, Lixian
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
Recommended Citation
GB/T 7714
Jiao, Chengli,Jiang, Xia,Chu, Hailiang,et al. A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties[J]. CRYSTENGCOMM,2016,18(44):8683-8687.
APA Jiao, Chengli,Jiang, Xia,Chu, Hailiang,Jiang, Heqing,&Sun, Lixian.(2016).A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties.CRYSTENGCOMM,18(44),8683-8687.
MLA Jiao, Chengli,et al."A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties".CRYSTENGCOMM 18.44(2016):8683-8687.
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