DICP OpenIR
Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis
Yu, Songjie1; Li, Yingzi2; Kong, Lingheng1; Zhou, Xukai1; Tang, Guodong1; Lan, Yu2; Li, Xingwei1
KeywordAcylation C-h Activation Rhodium Ketene Arene
Source PublicationACS CATALYSIS
2016-11-01
ISSN2155-5435
DOI10.1021/acscatal.6b02668
Volume6Issue:11Pages:7744-7748
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordC-H BOND ; ALPHA-OXOCARBOXYLIC ACIDS ; OXIDATIVE ORTHO-ACYLATION ; O-METHYL OXIMES ; DECARBOXYLATIVE ACYLATION ; PHOTOREDOX CATALYSIS ; TOLUENE DERIVATIVES ; DUAL ACTIVATION ; DIRECTING GROUP ; ALDEHYDES
AbstractCarbonyl groups are ubiquitous in functional molecules. Although C-H bond acylation has been well studied via different mechanisms, transition-metal-catalyzed redox-neutral C(sp(3))-H acylation under mild conditions is unprecedented. In this work, ketene is designed as a acylating reagent for both C(sp(3))-H and C(sp(2))-H bonds under Rh(III) catalysis, affording a diverse array of carbonyl compounds in high yields and high atom economy under mild conditions.
Language英语
WOS IDWOS:000387306100053
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169735
Collection中国科学院大连化学物理研究所
Corresponding AuthorLan, Yu; Li, Xingwei
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing, Peoples R China
Recommended Citation
GB/T 7714
Yu, Songjie,Li, Yingzi,Kong, Lingheng,et al. Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis[J]. ACS CATALYSIS,2016,6(11):7744-7748.
APA Yu, Songjie.,Li, Yingzi.,Kong, Lingheng.,Zhou, Xukai.,Tang, Guodong.,...&Li, Xingwei.(2016).Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis.ACS CATALYSIS,6(11),7744-7748.
MLA Yu, Songjie,et al."Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis".ACS CATALYSIS 6.11(2016):7744-7748.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yu, Songjie]'s Articles
[Li, Yingzi]'s Articles
[Kong, Lingheng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yu, Songjie]'s Articles
[Li, Yingzi]'s Articles
[Kong, Lingheng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yu, Songjie]'s Articles
[Li, Yingzi]'s Articles
[Kong, Lingheng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.