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Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60
Li, Yanbang1; Zhang, Gaihong1,3; Wang, Dian1; Xu, Beidi1; Xu, Dan1; Lou, Ning1; Gan, Liangbing1,2
KeywordCopper Complex Fullerenes Guanidine Heterocycles Macrocycle
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2016-11-14
ISSN1433-7851
DOI10.1002/anie.201606856
Volume55Issue:47Pages:14590-14594
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordOPEN-CAGE FULLERENES ; ARYLBORONIC ACIDS ; HETEROFULLERENES ; ENCAPSULATION ; ORIFICES ; PEROXIDE ; MOLECULE ; ANILINES ; HYDROGEN ; C58N2
AbstractA 14-membered heterocycle is created on the C-60 cage skeleton through a multistep procedure. Key steps involve repeated PCl5-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen atoms. The hetero atoms form one pyrrole, two pyran, and one diazepine rings in conjunction with the C-60 skeleton carbon atoms. The fullerene-based macrocycle showed unique reactivities towards fluoride ion and copper salts.
Language英语
WOS IDWOS:000388252700014
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169747
Collection中国科学院大连化学物理研究所
Corresponding AuthorGan, Liangbing
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
3.Zhengzhou Univ Light Ind, Sch Food & Bioengn, Zhengzhou 450002, Peoples R China
Recommended Citation
GB/T 7714
Li, Yanbang,Zhang, Gaihong,Wang, Dian,et al. Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(47):14590-14594.
APA Li, Yanbang.,Zhang, Gaihong.,Wang, Dian.,Xu, Beidi.,Xu, Dan.,...&Gan, Liangbing.(2016).Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(47),14590-14594.
MLA Li, Yanbang,et al."Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.47(2016):14590-14594.
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