DICP OpenIR
Synthesis of High-Density Aviation Fuel with Cyclopentanol
Chen, Fang1,3; Li, Ning1,2; Yang, Xiaofeng1; Li, Lin1; Li, Guangyi1; Li, Shanshan1,3; Wang, Wentao1; Hu, Yancheng1; Wang, Aiqin1,2; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1,2
KeywordJet Fuel Lignocellulose Cyclopentanol Dehydration Oligomerization/rearrangement Solid Acid Catalyst
Source PublicationACS SUSTAINABLE CHEMISTRY & ENGINEERING
2016-11-01
ISSN2168-0485
DOI10.1021/acssuschemeng.6b01678
Volume4Issue:11Pages:6160-6166
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordAROMATIC-HYDROCARBONS ; TRANSPORTATION FUELS ; CATALYTIC CONVERSION ; GAMMA-VALEROLACTONE ; PLATFORM MOLECULES ; LIQUID ALKANES ; JET-FUEL ; BIOMASS ; ACID ; LIGNOCELLULOSE
AbstractDecalin is the main component of JP-900, a thermally stable and high-energy density jet fuel. Decalin is also an important component of advanced jet fuels. Cyclopentanol is a platform compound that can be derived from lignocellulose. In this work, a mixture of C-10 and C-15 polycycloalkanes (with decalin as the major component) was first synthesized by the oligomerization/rearrangement of cyclopentene from the dehydration of cyclopentanol, followed by hydrogenation. Among the investigated catalysts, Amberlyst-36 resin demonstrated the highest activity and excellent stability for cyclopentanol dehydration and cyclopentene oligomerization/rearrangement. The influences of reaction temperature and reaction time on the catalytic performances of Amberlyst-36 resin for both reactions were investigated. Under the optimum conditions, 84.0% carbon yield of cyclopentene was obtained from cyclopentanol dehydration, and 74.2% carbon yield of C-10 and C-15 polycycloalkenes was achieved by the oligomerization/rearrangement of cyclopentene. Finally, the C-10 and C-15 polycycloalkenes from the oligomerization/rearrangement of cyclopentene were further hydrogenated to a mixture of C-10 and C-15 polycycloalkanes with decalin as the major component (77% selectivity). This polycycloalkane mixture has high density (0.896 g mL(-1)). As a potential application, it can be used as an additive to improve the volumetric calorific values of conventional biojet fuels.
Language英语
WOS IDWOS:000387428700042
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/169791
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Ning; Zhang, Tao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Chen, Fang,Li, Ning,Yang, Xiaofeng,et al. Synthesis of High-Density Aviation Fuel with Cyclopentanol[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(11):6160-6166.
APA Chen, Fang.,Li, Ning.,Yang, Xiaofeng.,Li, Lin.,Li, Guangyi.,...&Zhang, Tao.(2016).Synthesis of High-Density Aviation Fuel with Cyclopentanol.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(11),6160-6166.
MLA Chen, Fang,et al."Synthesis of High-Density Aviation Fuel with Cyclopentanol".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.11(2016):6160-6166.
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