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Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins
Dai, Wen; Mi, Yuan; Lv, Ying; Shang, Sensen; Li, Guosong; Chen, Guangwen1; Gao, Shuang1
KeywordContinuous Flow Microreactor Asymmetric Epoxidation Iron Catalysis Electron-deficient Olefins Biomimetic Catalyst
Source PublicationSYNTHESIS-STUTTGART
2016-08-01
ISSN0039-7881
DOI10.1055/s-0035-1561955
Volume48Issue:16Pages:2653-2658
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordINSPIRED MANGANESE COMPLEX ; HIGHLY STEREOSELECTIVE EPOXIDATION ; AQUEOUS HYDROGEN-PEROXIDE ; WIDE SUBSTRATE SCOPE ; ENANTIOSELECTIVE EPOXIDATION ; ALPHA,BETA-UNSATURATED KETONES ; CHIRAL KETONES ; CATALYSTS ; ALKENES ; OXIDATION
AbstractAsymmetric epoxidation of electron-deficient olefins catalyzed by a biomimetic iron complex in a continuous-flow microreactor is described. The reaction conducted in the microreactor is characterized by rapid (<4 min) epoxidation of trisubstituted enones in high yields (up to 90%) and excellent enantioselectivities (up to 92% ee); compared to its batchwise counterpart, the microreactor reaction also allows shorter reaction times, safer operation, and more precise control over the reaction conditions.
Language英语
WOS IDWOS:000382509100014
PublisherGEORG THIEME VERLAG KG
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170043
Collection中国科学院大连化学物理研究所
Corresponding AuthorChen, Guangwen; Gao, Shuang
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Dai, Wen,Mi, Yuan,Lv, Ying,et al. Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins[J]. SYNTHESIS-STUTTGART,2016,48(16):2653-2658.
APA Dai, Wen.,Mi, Yuan.,Lv, Ying.,Shang, Sensen.,Li, Guosong.,...&Gao, Shuang.(2016).Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins.SYNTHESIS-STUTTGART,48(16),2653-2658.
MLA Dai, Wen,et al."Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins".SYNTHESIS-STUTTGART 48.16(2016):2653-2658.
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