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Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction
Jiang, Yu1,2; Xie, Yan2; Jin, Xinxin2; Hu, Qi2; Chen, Li3; Xu, Ling1; Huang, Jiahui2
Source PublicationRSC ADVANCES
2016
ISSN2046-2069
DOI10.1039/c6ra13106a
Volume6Issue:82Pages:78737-78742
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordNITROGEN-DOPED CARBON ; REDUCED GRAPHENE OXIDE ; ELECTROLYTE FUEL-CELLS ; NONPRECIOUS CATALYST ; MESOPOROUS CARBON ; CATHODE CATALYST ; NANOPARTICLES ; ARCHITECTURES ; PERFORMANCE ; ELECTROREDUCTION
AbstractPorous carbon (PC) materials with a large surface area and uniform pore sizes have been used as novel electrocatalysts to catalyze the oxygen reduction reaction (ORR). In this work, iron phthalocyanine (FePc) and magnesium oxide (MgO) were used as the precursors and hard-template, respectively, to fabricate FePc-based porous carbon non-noble metal electrocatalysts (NNMEs). The prepared FePc-based porous carbon electrocatalysts possess a high surface area of 555 m(2) g(-1) and a dual mesoporous structure with mean pore sizes of 3.6 nm and 32 nm, and display comparable ORR activity but superior durability than a commercial Pt/C electrocatalyst in alkaline solution. The excellent catalytic performance of FePc-based porous carbon electrocatalysts may be attributed to the large surface area, high density of iron based nano-particles (NPs) encapsulated in carbon layers and high content of doped nitrogen species.
Language英语
WOS IDWOS:000382539300059
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170211
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu, Ling; Huang, Jiahui
Affiliation1.Inner Mongolia Univ Nationalities, Coll Chem & Chem Engn, Xilamulun St 996, Tongliao 028000, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.East China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, North Zhongshan Rd 3663, Shanghai 200062, Peoples R China
Recommended Citation
GB/T 7714
Jiang, Yu,Xie, Yan,Jin, Xinxin,et al. Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction[J]. RSC ADVANCES,2016,6(82):78737-78742.
APA Jiang, Yu.,Xie, Yan.,Jin, Xinxin.,Hu, Qi.,Chen, Li.,...&Huang, Jiahui.(2016).Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction.RSC ADVANCES,6(82),78737-78742.
MLA Jiang, Yu,et al."Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction".RSC ADVANCES 6.82(2016):78737-78742.
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