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Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis
Yu, Songjie1; Tang, Guodong1; Li, Yingzi2; Zhou, Xukai1; Lan, Yu2; Li, Xingwei1
KeywordAmination Arenes C-h Activation Reaction Mechanisms Rhodium
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2016-07-18
ISSN1433-7851
DOI10.1002/anie.201602224
Volume55Issue:30Pages:8696-8700
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordC-H AMINATION ; CARBON-NITROGEN BONDS ; INTERMOLECULAR AMIDATION ; COUPLING REACTIONS ; INTRAMOLECULAR C(SP(3))-H ; ROOM-TEMPERATURE ; ACTIVATION ; AZIDES ; ALKYNES ; ARENES
AbstractPrevious direct C-H nitrogenation suffered from simple amidation/amination with limited atom-economy and is mostly limited to C(sp(2))-H substrates. In this work, anthranil was designed as a novel bifunctional aminating reagent for both C(sp(2)) H and C(sp(3)) H bonds under rhodium(III) catalysis, thus affording a nucleophilic aniline tethered to an electrophilic carbonyl. A tridendate rhodium(III) complex has been isolated as the resting state of the catalyst, and DFT studies established the intermediacy of a nitrene species.
Language英语
WOS IDWOS:000383253500038
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:95[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170219
Collection中国科学院大连化学物理研究所
Corresponding AuthorLan, Yu; Li, Xingwei
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China
Recommended Citation
GB/T 7714
Yu, Songjie,Tang, Guodong,Li, Yingzi,et al. Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(30):8696-8700.
APA Yu, Songjie,Tang, Guodong,Li, Yingzi,Zhou, Xukai,Lan, Yu,&Li, Xingwei.(2016).Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(30),8696-8700.
MLA Yu, Songjie,et al."Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.30(2016):8696-8700.
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