DICP OpenIR
Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose
Sheng, Xueru1,2; Li, Guangyi1; Wang, Wentao1; Cong, Yu1; Wang, Xiaodong1; Huber, George W.3; Li, Ning1,4; Wang, Aiqin1,4; Zhang, Tao1,4
KeywordLignocellulose High Density Aviation Fuel Aldol Condensation Hydrodeoxygenation Dual-bed Continuous Flow Reactor
Source PublicationAICHE JOURNAL
2016-08-01
ISSN0001-1541
DOI10.1002/aic.15248
Volume62Issue:8Pages:2754-2761
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
WOS SubjectEngineering, Chemical
WOS Research AreaEngineering
WOS KeywordHIGH-QUALITY DIESEL ; SELECTIVE HYDROGENATION ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; BIODIESEL PRODUCTION ; SINGLE-REACTOR ; LIQUID ALKANES ; RANGE ALKANES ; BIOMASS ; CONVERSION
AbstractIn this article, we demonstrated an integrated process for the direct production of tri(cyclopentane) with cyclopentanone which can be obtained from lignocellulose. The reaction was carried out in a dual-bed continuous flow reactor. In the first bed, cyclopentanone was selectively converted to 2,5-dicyclopentylcyclopentanol over the Pd-MgAl-HT (hydrotalcite) catalyst. Under solvent-free and mild conditions (443 K, 0.1 MPa H-2), high carbon yield (81.2%) of 2,5-dicyclopentylcyclopentanol was achieved. Subsequently, the 2,5-dicyclopentylcyclopentanol was further hydrodeoxygenated to tri(cyclopentane) in the second bed. Among the investigated catalysts, the Ni-H beta-DP prepared by deposition-precipitation (DP) method exhibited the highest activity for the hydrodeoxygenation step. By using Pd-MgAl-HT as the first bed catalyst and Ni-HbDP as the second bed catalyst, tri(cyclopentane) was directly produced at high carbon yield (80.0%) with cyclopentanone as feedstock. This polycycloalkane has high density (0.91 kg/L) and can be used as additive to improve the density and volumetric heating value of bio-jet fuel. (C) 2016 American Institute of Chemical Engineers
Language英语
WOS IDWOS:000382986000014
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170223
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Ning; Zhang, Tao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
3.Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA
4.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Sheng, Xueru,Li, Guangyi,Wang, Wentao,et al. Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose[J]. AICHE JOURNAL,2016,62(8):2754-2761.
APA Sheng, Xueru.,Li, Guangyi.,Wang, Wentao.,Cong, Yu.,Wang, Xiaodong.,...&Zhang, Tao.(2016).Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose.AICHE JOURNAL,62(8),2754-2761.
MLA Sheng, Xueru,et al."Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose".AICHE JOURNAL 62.8(2016):2754-2761.
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