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Cooperative Co(III)/Cu(II)-Catalyzed C-N/N-N Coupling of Imidates with Anthranils: Access to 1H-Indazoles via C-H Activation
Li, Lei; Wang, He; Yu, Songjie; Yang, Xifa; Li, Xingwei
Source PublicationORGANIC LETTERS
2016-08-05
ISSN1523-7060
DOI10.1021/acs.orglett.6b01716
Volume18Issue:15Pages:3662-3665
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordBOND FUNCTIONALIZATION ; MILD CONDITIONS ; COBALT(III)-CATALYZED SYNTHESIS ; AROMATIC KETONES ; DIAZO-COMPOUNDS ; AMINO SOURCES ; AMIDATION ; INDOLES ; ALKYNES ; ARENES
AbstractCooperative cobalt- and copper-catalyzed C-H activation of imidate esters and oxidative coupling with anthranils allowed efficient synthesis of 1H-indazoles in the absence of metal oxidants. The anthranil acts as a convenient aminating reagent as well as an organic oxidant in this transformation. The copper catalyst likely functions at the stage of N-N formation.
Language英语
WOS IDWOS:000381236300039
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:69[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170319
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Xingwei
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Li, Lei,Wang, He,Yu, Songjie,et al. Cooperative Co(III)/Cu(II)-Catalyzed C-N/N-N Coupling of Imidates with Anthranils: Access to 1H-Indazoles via C-H Activation[J]. ORGANIC LETTERS,2016,18(15):3662-3665.
APA Li, Lei,Wang, He,Yu, Songjie,Yang, Xifa,&Li, Xingwei.(2016).Cooperative Co(III)/Cu(II)-Catalyzed C-N/N-N Coupling of Imidates with Anthranils: Access to 1H-Indazoles via C-H Activation.ORGANIC LETTERS,18(15),3662-3665.
MLA Li, Lei,et al."Cooperative Co(III)/Cu(II)-Catalyzed C-N/N-N Coupling of Imidates with Anthranils: Access to 1H-Indazoles via C-H Activation".ORGANIC LETTERS 18.15(2016):3662-3665.
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