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Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance
Xu, Dan1,2; Sun, Lei1; Li, Gang3; Shang, Jin4; Yang, Rui-Xia1; Deng, Wei-Qiao1
KeywordDoping Hydrogen Microporous Materials Polymers Quantum Chemistry
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
2016-06-01
ISSN0947-6539
DOI10.1002/chem.201504666
Volume22Issue:23Pages:7944-7949
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMETAL-ORGANIC FRAMEWORKS ; POROUS AROMATIC FRAMEWORKS ; CARBON-BASED MATERIALS ; HIGH-SURFACE-AREA ; GAS-STORAGE ; UPTAKE CAPACITIES ; LITHIUM IONS ; ADSORPTION ; ALKALI ; LI
AbstractHydrogen storage is a primary challenge for using hydrogen as a fuel. With ideal hydrogen storage kinetics, the weak binding strength of hydrogen to sorbents is the key barrier to obtain decent hydrogen storage performance. Here, we reported the rational synthesis of a methyllithium-doped naphthyl-containing conjugated microporous polymer with exceptional binding strength of hydrogen to the polymer guided by theoretical simulations. Meanwhile, the experimental results showed that isosteric heat can reach up to 8.4 kJ mol(-1) and the methyllithium-doped naphthyl-containing conjugated microporous polymer exhibited an enhanced hydrogen storage performance with 150% enhancement compared with its counterpart naphthyl-containing conjugated microporous polymer. These results indicate that this strategy provides a direction for design and synthesis of new materials that meet the US Department of Energy (DOE) hydrogen storage target.
Language英语
WOS IDWOS:000380267100037
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170345
Collection中国科学院大连化学物理研究所
Corresponding AuthorDeng, Wei-Qiao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
3.Univ Western Australia, Sch Mech & Chem Engn, 35 Stirling Highway, Crawley, WA 6009, Australia
4.Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia
Recommended Citation
GB/T 7714
Xu, Dan,Sun, Lei,Li, Gang,et al. Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(23):7944-7949.
APA Xu, Dan,Sun, Lei,Li, Gang,Shang, Jin,Yang, Rui-Xia,&Deng, Wei-Qiao.(2016).Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance.CHEMISTRY-A EUROPEAN JOURNAL,22(23),7944-7949.
MLA Xu, Dan,et al."Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance".CHEMISTRY-A EUROPEAN JOURNAL 22.23(2016):7944-7949.
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