DICP OpenIR
Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction
Leng, Wenguang1; Peng, Yongsheng1; Zhang, Jianqiang1; Lu, Hui1; Feng, Xiao2; Ge, Rile1; Dong, Bin1; Wang, Bo2; Hu, Xiangping1; Gao, Yanan1
KeywordCascade Reactions Covalent Organic Frameworks Heterogeneous Catalysis Metal Loading Nitrogen Ligands
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
2016-06-27
ISSN0947-6539
DOI10.1002/chem.201601334
Volume22Issue:27Pages:9087-9091
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordSTORAGE ; CATALYSIS ; HYDROGEN ; COMPLEXES ; POLYMERS ; LIGANDS
AbstractPrecise control of the number and position of the catalytic metal ions in heterogeneous catalysts remains a big challenge. Here we synthesized a series of two-dimensional (2D) covalent organic frameworks (COFs) containing two different types of nitrogen ligands, namely imine and bipyridine, with controllable contents. For the first time, the selective coordination of the two nitrogen ligands of the 2D COFs to two different metal complexes, chloro(1,5-cyclooctadiene)rhodium(I) (Rh(COD) Cl) and palladium(II) acetate (Pd(OAc)(2)), has been realized using a programmed synthetic procedure. The bimetallically docked COFs showed excellent catalytic activity in a one-pot addition-oxidation cascade reaction. The high surface area, controllable metal-loading content, and predesigned active sites make them ideal candidates for their use as heterogeneous catalysts in a wide range of chemical reactions.
Language英语
WOS IDWOS:000380271100009
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170347
Collection中国科学院大连化学物理研究所
Corresponding AuthorGao, Yanan
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Beijing Inst Technol, Sch Chem, Key Lab Cluster Sci, Minist Educ China, 5 South Zhongguancun St, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Leng, Wenguang,Peng, Yongsheng,Zhang, Jianqiang,et al. Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(27):9087-9091.
APA Leng, Wenguang.,Peng, Yongsheng.,Zhang, Jianqiang.,Lu, Hui.,Feng, Xiao.,...&Gao, Yanan.(2016).Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction.CHEMISTRY-A EUROPEAN JOURNAL,22(27),9087-9091.
MLA Leng, Wenguang,et al."Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction".CHEMISTRY-A EUROPEAN JOURNAL 22.27(2016):9087-9091.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Leng, Wenguang]'s Articles
[Peng, Yongsheng]'s Articles
[Zhang, Jianqiang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Leng, Wenguang]'s Articles
[Peng, Yongsheng]'s Articles
[Zhang, Jianqiang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Leng, Wenguang]'s Articles
[Peng, Yongsheng]'s Articles
[Zhang, Jianqiang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.