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Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent
Zhang, Miao1,2; Liu, Lin1; He, Teng1; Wu, Guotao1; Chen, Ping1
Keyword2d Carbonaceous Polymer Nanosheets Carbon Dioxide Capture Ionothermal Method Microporous Materials Polymers
Source PublicationCHEMISTRY-AN ASIAN JOURNAL
2016-06-21
ISSN1861-4728
DOI10.1002/asia.201600396
Volume11Issue:12Pages:1849-1855
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCOVALENT ORGANIC FRAMEWORKS ; TRIAZINE-BASED FRAMEWORKS ; ON-SURFACE SYNTHESIS ; IONOTHERMAL SYNTHESIS ; DIOXIDE CAPTURE ; THIN-FILMS ; AIR/WATER INTERFACE ; LARGE-AREA ; GRAPHENE ; CAPACITY
AbstractThe synthesis of two-dimensional (2D) polymer nanosheets with a well-defined microporous structure remains challenging in materials science. Here, a new kind of 2D microporous carbonaceous polymer nanosheets was synthesized through polymerization of a very low concentration of 1,4-dicyanobenzene in molten zinc chloride at 400-500 degrees C. This type of nanosheets has a thickness in the range of 3-20nm, well-defined microporosity, a high surface area (approximate to 537m(2)g(-1)), and a large micropore volume (approximate to 0.45cm(3)g(-1)). The microporous carbonaceous polymer nanosheets exhibit superior CO2 sorption capability (8.14wt% at 298K and 1bar) and a relatively high CO2 selectivity toward N-2 (25.6). Starting from different aromatic nitrile monomers, a variety of 2D carbonaceous polymer nanosheets can be obtained showing a certain universality of the ionothermal method reported herein.
Language英语
WOS IDWOS:000379519400016
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170411
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Lin; Chen, Ping
Affiliation1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Miao,Liu, Lin,He, Teng,et al. Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(12):1849-1855.
APA Zhang, Miao,Liu, Lin,He, Teng,Wu, Guotao,&Chen, Ping.(2016).Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent.CHEMISTRY-AN ASIAN JOURNAL,11(12),1849-1855.
MLA Zhang, Miao,et al."Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent".CHEMISTRY-AN ASIAN JOURNAL 11.12(2016):1849-1855.
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