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Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template
Zhang, Bin1,2,3; Li, Xiaoru1,2,3; Wu, Qifan1,2,3; Zhang, Chao1,2; Yu, Yancun1,2,3; Lan, Mingli1,2; Wei, Xing3; Ying, Zhong1,2,3; Liu, Tong1,2,3; Liang, Guanfeng4; Zhao, Fengyu1,2
Source PublicationGREEN CHEMISTRY
2016-06-07
ISSN1463-9262
DOI10.1039/c5gc03077c
Volume18Issue:11Pages:3315-3323
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHYDROLYTIC HYDROGENATION ; LIGNOCELLULOSIC BIOMASS ; BIMETALLIC CATALYSTS ; SELECTIVE CONVERSION ; HIGH-YIELD ; SORBITOL ; ZEOLITE ; GLUCOSE ; SURFACE ; WATER
AbstractEfficient utilization of cellulose is of scientific significance and a great challenge for both fundamental and industrial studies. Herein, we synthesized MesoZSM-5 zeolites by using nanocrystalline cellulose as a template for the first time, and reported the exciting performance of the corresponding non-noble metal catalysts (Ni/MesoZSM-5) for efficient conversion of cellulose to hexitols. By modulating the ratio of the template to precursor, MesoZSM-5 supports were produced with tunable pore structure and acidic sites. With the cooperation of active Ni sites and acidic sites of MesoZSM-5, hexitols were obtained with a high yield of around 60% in the direct conversion of commercial microcrystalline cellulose (MCC). The corresponding correlation between the structural characteristics and catalytic performance was established. This work provides a new approach for efficient utilization of cellulose, as well as gives rise to a sustainable templating method for the synthesis of mesoporous zeolites.
Language英语
WOS IDWOS:000378178200016
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170535
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Chao; Zhao, Fengyu
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Bin,Li, Xiaoru,Wu, Qifan,et al. Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template[J]. GREEN CHEMISTRY,2016,18(11):3315-3323.
APA Zhang, Bin.,Li, Xiaoru.,Wu, Qifan.,Zhang, Chao.,Yu, Yancun.,...&Zhao, Fengyu.(2016).Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template.GREEN CHEMISTRY,18(11),3315-3323.
MLA Zhang, Bin,et al."Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template".GREEN CHEMISTRY 18.11(2016):3315-3323.
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