DICP OpenIR
Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening
Zhou, Xukai; Yu, Songjie; Qi, Zisong; Kong, Lingheng; Li, Xingwei
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2016-06-03
ISSN0022-3263
DOI10.1021/acs.joc.6b00650
Volume81Issue:11Pages:4869-4875
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPALLADIUM-CATALYZED REACTIONS ; BOND FORMATION ; CONJUGATE ADDITION ; ALLYLIC ALKYLATION ; C(SP(3))-H BONDS ; INDOLE ALKALOIDS ; ARYL BROMIDES ; ARENES ; FUNCTIONALIZATION ; ARYLATION
AbstractThe rhodium(III)-catalyzed regioselective alkylation of (hetero)arenes using cyclopropanols as a reactive and efficient coupling, partner under oxidative conditions has been developed. This coupling occurred at room temperature via C-H activation of arenes and C-C cleavage of cyclopropanols. Various types of (hetero)arenes (indolines, carbazole, tetrahydrocarbazole, pyrrole, thiophene, etc.) were all successfully reacted under the present conditions. This protocol provides the facile and efficient construction of C7-alkylated indoline scaffolds.
Language英语
WOS IDWOS:000377319500048
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170611
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Xingwei
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Xukai,Yu, Songjie,Qi, Zisong,et al. Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(11):4869-4875.
APA Zhou, Xukai,Yu, Songjie,Qi, Zisong,Kong, Lingheng,&Li, Xingwei.(2016).Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening.JOURNAL OF ORGANIC CHEMISTRY,81(11),4869-4875.
MLA Zhou, Xukai,et al."Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening".JOURNAL OF ORGANIC CHEMISTRY 81.11(2016):4869-4875.
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