DICP OpenIR
Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3
Yang, Yanliang1,2; Ma, Jiping1; Jia, Xiuquan1,3; Du, Zhongtian1; Duan, Ying2; Xu, Jie1
Source PublicationRSC ADVANCES
2016
ISSN2046-2069
DOI10.1039/c6ra05680f
Volume6Issue:56Pages:51221-51228
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCATALYTIC-HYDROGENATION ; ALLOY CATALYST ; CONVERSION ; BIOMASS ; CHEMICALS ; TRANSFORMATION ; HYDROGENOLYSIS ; CYCLOPENTANONE ; REDUCTION ; PLATFORM
AbstractAl2O3 modified by alkaline earth metals M-Al2O3 (M - Mg, Ca, Sr, Ba) was synthesised by coprecipitation method. The nickel-based catalysts supported by M-Al2O3 were prepared by impregnation method. The catalysts were characterized by TEM, N-2 adsorption/desorption, XRD, H-2-TPR, NH3-TPD and XPS, and used for the direct hydrogenation of furfural to tetrahydrofurfuryl alcohol (THFA) in water. The reaction was demonstrated to proceed through furfuryl alcohol as an intermediate. The modification of Al2O3 by alkaline earth metals has a significant effect on the activity and selectivity of THFA. A high yield of THFA was obtained over Ni/Ba-Al2O3 under optimized conditions. Moreover, the catalyst is recyclable and reusable at least four times without significant loss of the conversion of furfural and selectivity of THFA.
Language英语
WOS IDWOS:000377515200093
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/170629
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu, Jie
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,et al. Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3[J]. RSC ADVANCES,2016,6(56):51221-51228.
APA Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,Du, Zhongtian,Duan, Ying,&Xu, Jie.(2016).Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3.RSC ADVANCES,6(56),51221-51228.
MLA Yang, Yanliang,et al."Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3".RSC ADVANCES 6.56(2016):51221-51228.
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