DICP OpenIR
Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones
Jiang, Quanbin1; Guo, Tenglong1; Wu, Kaikai1; Yu, Zhengkun1,2
Source PublicationCHEMICAL COMMUNICATIONS
2016
ISSN1359-7345
DOI10.1039/c5cc10361d
Volume52Issue:14Pages:2913-2915
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCONJUGATE ADDITION ; MILD CONDITIONS ; DIRECTING GROUP ; BETA,BETA-DISUBSTITUTED ENONES ; SELECTIVE FUNCTIONALIZATION ; ENANTIOSELECTIVE SYNTHESIS ; CONVERGENT SYNTHESIS ; ASYMMETRIC-SYNTHESIS ; FLUOROALKYL GROUP ; ACTIVATION
AbstractRhodium(III)-catalyzed conjugate addition of aromatic and olefinic C-H bonds to CF3-substituted unsaturated ketones was efficiently achieved. Both arene and olefin substrates bearing a chelate assisted-directing group were coupled with a variety of beta-trifluoromethyl-alpha,beta-unsaturated ketones with excellent atom-economy, high yields, and broad substrate scopes.
Language英语
WOS IDWOS:000369641300009
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171169
Collection中国科学院大连化学物理研究所
Corresponding AuthorYu, Zhengkun
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Jiang, Quanbin,Guo, Tenglong,Wu, Kaikai,et al. Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones[J]. CHEMICAL COMMUNICATIONS,2016,52(14):2913-2915.
APA Jiang, Quanbin,Guo, Tenglong,Wu, Kaikai,&Yu, Zhengkun.(2016).Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones.CHEMICAL COMMUNICATIONS,52(14),2913-2915.
MLA Jiang, Quanbin,et al."Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones".CHEMICAL COMMUNICATIONS 52.14(2016):2913-2915.
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