DICP OpenIR
Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons
Li, Yanbang1; Xu, Dan1; Gan, Liangbing1,2
KeywordAmination Conjugation Fullerenes Nucleophilic Addition X-ray Diffraction
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2016-02-12
ISSN1433-7851
DOI10.1002/anie.201510872
Volume55Issue:7Pages:2483-2487
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordFULLERENE CHEMISTRY ; SOLAR-CELLS ; C-60 ; REGIOCHEMISTRY ; AMINE ; FUNCTIONALIZATION ; DERIVATIVES ; CYCLOPHANE ; COMPLEXES ; ADDITIONS
AbstractSecondary aliphatic amines add to a pole pentagon of [70] fullerene in the presence of N-fluorobenzenesulfonimide to form cyclopentadienyl-type adducts, C-70(NSO2Ph)( NR1R2) 4 (1), which can be converted into analogous C-70 derivatives such as C-70(NHSO2Ph)(NHTol) 5 (2). Further addition reactions of either 1 or 2 take place selectively at the opposite pole pentagon of the C-70 'cage, thus forming curved p systems with a reduced number of p electrons, and the products include a dodecakis-adduct with a Vogtle belt motif.
Language英语
WOS IDWOS:000369970500033
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171251
Collection中国科学院大连化学物理研究所
Corresponding AuthorGan, Liangbing
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Li, Yanbang,Xu, Dan,Gan, Liangbing. Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(7):2483-2487.
APA Li, Yanbang,Xu, Dan,&Gan, Liangbing.(2016).Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(7),2483-2487.
MLA Li, Yanbang,et al."Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.7(2016):2483-2487.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Yanbang]'s Articles
[Xu, Dan]'s Articles
[Gan, Liangbing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Yanbang]'s Articles
[Xu, Dan]'s Articles
[Gan, Liangbing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Yanbang]'s Articles
[Xu, Dan]'s Articles
[Gan, Liangbing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.