DICP OpenIR
Iridium(III)- and rhodium(III)- catalyzed coupling of anilines with alpha-diazoesters via chelation- assisted C-H activation
Tang, Guo-Dong1,2; Pan, Cheng-Ling2; Li, Xingwei2
Source PublicationORGANIC CHEMISTRY FRONTIERS
2016
ISSN2052-4129
DOI10.1039/c5qo00316d
Volume3Issue:1Pages:87-90
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordNONREARRANGED MONOTERPENOID UNIT ; FISCHER INDOLE SYNTHESIS ; N BOND FORMATION ; INTERNAL ALKYNES ; DIAZO-COMPOUNDS ; RH(III)-CATALYZED SYNTHESIS ; DIVERGENT SYNTHESIS ; NITROGEN-SOURCE ; FUNCTIONALIZATION ; ANNULATION
AbstractIridium and rhodium complexes exhibited complementary activity in the coupling of N-functionalized anilines with alpha-diazoesters via C-H activation. The coupling with alpha-diazo beta-ketoesters was realized under Ir(III) catalysis to afford ester-functionalized indoles. In contrast, coupling with alpha-diazomalonates under Rh(III) catalysis afforded alkylation products without any annulation. Mechanistic studies have been performed and an iridacycle has been isolated as an intermediate.
Language英语
WOS IDWOS:000366864700014
PublisherCHINESE CHEMICAL SOC
Citation statistics
Cited Times:47[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171573
Collection中国科学院大连化学物理研究所
Corresponding AuthorTang, Guo-Dong
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Anhui Univ Sci & Technol, Lab Multi Scale Mat & Mol Catalysis, Sch Mat Sci & Engn, Huainan 232001, Peoples R China
Recommended Citation
GB/T 7714
Tang, Guo-Dong,Pan, Cheng-Ling,Li, Xingwei. Iridium(III)- and rhodium(III)- catalyzed coupling of anilines with alpha-diazoesters via chelation- assisted C-H activation[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(1):87-90.
APA Tang, Guo-Dong,Pan, Cheng-Ling,&Li, Xingwei.(2016).Iridium(III)- and rhodium(III)- catalyzed coupling of anilines with alpha-diazoesters via chelation- assisted C-H activation.ORGANIC CHEMISTRY FRONTIERS,3(1),87-90.
MLA Tang, Guo-Dong,et al."Iridium(III)- and rhodium(III)- catalyzed coupling of anilines with alpha-diazoesters via chelation- assisted C-H activation".ORGANIC CHEMISTRY FRONTIERS 3.1(2016):87-90.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Tang, Guo-Dong]'s Articles
[Pan, Cheng-Ling]'s Articles
[Li, Xingwei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Tang, Guo-Dong]'s Articles
[Pan, Cheng-Ling]'s Articles
[Li, Xingwei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Tang, Guo-Dong]'s Articles
[Pan, Cheng-Ling]'s Articles
[Li, Xingwei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.