DICP OpenIR
Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway
Zhou, Xiao-Le1,2; Yang, Fan1; Sun, Han-Li1; Yin, Yun-Nian1; Ye, Wei-Ting1; Zhu, Rong1
Corresponding AuthorZhu, Rong(rongzhu@pku.edu.cn)
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2019-05-08
ISSN0002-7863
DOI10.1021/jacs.9b01857
Volume141Issue:18Pages:7250-7255
Funding ProjectCollege of Chemistry and Molecular Engineering, Peking University ; BNLMS
Funding OrganizationCollege of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMARKOVNIKOV-SELECTIVE HYDROFUNCTIONALIZATION ; HETEROATOM BOND FORMATION ; UNACTIVATED OLEFINS ; ELECTRON-TRANSFER ; CARBOXYLIC-ACIDS ; OXIDATION ; HYDROAMINATION ; COMPLEXES ; FE ; ORGANOCOBALT(IV)
AbstractA functional group tolerant cobalt-catalyzed method for the intermolecular hydrofunctionalization of alkenes with oxygen- and nitrogen-based nucleophiles is reported. This protocol features a strategic use of hypervalent iodine(III) reagents that enables a mechanistic shift from conventional cobalt-hydride catalysis. Key evidence was found supporting a unique bimetallic-mediated rate-limiting step involving two distinct cobalt(III) species, from which a new carbon-heteroatom bond is formed.
Language英语
Funding OrganizationCollege of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS
WOS IDWOS:000467781600006
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171838
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhu, Rong
Affiliation1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol ABCT, Hong Kong, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Xiao-Le,Yang, Fan,Sun, Han-Li,et al. Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2019,141(18):7250-7255.
APA Zhou, Xiao-Le,Yang, Fan,Sun, Han-Li,Yin, Yun-Nian,Ye, Wei-Ting,&Zhu, Rong.(2019).Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,141(18),7250-7255.
MLA Zhou, Xiao-Le,et al."Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141.18(2019):7250-7255.
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