DICP OpenIR
Persistent zinc-ion storage in mass-produced V2O5 architecture
Chen, Dong1; Rui, Xianhong1,2; Zhang, Qi1; Geng, Hongbo1; Gan, Liyong3,4; Zhang, Wei1; Li, Chengchao1; Huang, Shaoming1; Yu, Yan2,5,6
Corresponding AuthorRui, Xianhong(xhrui@gdut.edu.cn) ; Huang, Shaoming(smhuang@gdut.edu.cn) ; Yu, Yan(yanyumse@ustc.edu.cn)
KeywordMass production Zinc-ion battery V2O5 cathode Porous structure High performance
Source PublicationNANO ENERGY
2019-06-01
ISSN2211-2855
DOI10.1016/j.nanoen.2019.03.034
Volume60Pages:171-178
Funding ProjectNational Key R&D Research Program of China[2018YFB0905400] ; National Natural Science Foundation of China[51622210] ; National Natural Science Foundation of China[51872277] ; National Natural Science Foundation of China[21606003] ; National Natural Science Foundation of China[51802044] ; National Natural Science Foundation of China[51420105002] ; DNL cooperation Fund, CAS[DNL180310] ; Fundamental Research Funds for the Central Universities[WK3430000004] ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion
Funding OrganizationNational Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS KeywordVANADIUM PENTOXIDE ; CATHODE MATERIALS ; ELECTROCHEMICAL PROPERTIES ; AB-INITIO ; BATTERY ; INTERCALATION ; LI ; HEXACYANOFERRATE ; TRANSFORMATION ; CHEMISTRY
AbstractRechargeable zinc-ion batteries (ZIBs) appear to be a promising candidate for large-scale energy storage system because of the abundance and inherent safety of the zinc negative electrode. Despite these benefits, huge polarization caused by the intercalation of multivalent charge carrier Zn2+ into the cathodic hosts remains a long-standing challenge impeding the development of high-performance ZIBs. Herein, we demonstrate the viability of the V2O5 nanorods constructed 3D porous architectures (3D-NRAs-V2O5 ) as cathode for ZIBs. Notably, the 3D-NRAs-V2O5 can be scaled up to kilo-gram production based on a simple sol-gel reaction followed by an annealing process. The synergic contributions from the 3D porous framework and layered structures of the 3D-NRAs-V2O5 lead a more facile Zn2+ ions (de)intercalation storage process. Consequently, it offers high reversible capacity of 336 mAh g at a high current density of 50 mA g(-1) and exhibits excellent long-term cyclic stability with a capacity retention of 85% over 5000 cycles at a high current density of 10 A g(-1). Furthermore, the use of various ex-situ characterization techniques and first-principles calculations has successfully unravelled the Zn(2+)ions storage mechanism of the 3D-NRAs-V2O5 Besides the excellent electrochemical performance of the 3D-NRAs-V2O5, it can also be easily scaled up based on the simple synthetic protocol, which shows great potential to be practically used for the next-generation large-scale energy storage applications.
Language英语
Funding OrganizationNational Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion
WOS IDWOS:000467774100021
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171840
Collection中国科学院大连化学物理研究所
Corresponding AuthorRui, Xianhong; Huang, Shaoming; Yu, Yan
Affiliation1.Guangdong Univ Technol, Collaborat Innovat Ctr Adv Energy Mat, Sch Mat & Energy, Guangzhou Key Lab Low Dimens Mat & Energy Storage, Guangzhou 510006, Guangdong, Peoples R China
2.Univ Sci & Technol China, Key Lab Mat Energy Convers, Dept Mat Sci & Engn, Hefei Natl Lab Phys Sci Microscale,Chinese Acad S, Hefei 230026, Anhui, Peoples R China
3.Chongqing Univ, Inst Struct & Funct, Chongqing 400030, Peoples R China
4.Chongqing Univ, Dept Phys, Chongqing 400030, Peoples R China
5.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China
6.Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
Recommended Citation
GB/T 7714
Chen, Dong,Rui, Xianhong,Zhang, Qi,et al. Persistent zinc-ion storage in mass-produced V2O5 architecture[J]. NANO ENERGY,2019,60:171-178.
APA Chen, Dong.,Rui, Xianhong.,Zhang, Qi.,Geng, Hongbo.,Gan, Liyong.,...&Yu, Yan.(2019).Persistent zinc-ion storage in mass-produced V2O5 architecture.NANO ENERGY,60,171-178.
MLA Chen, Dong,et al."Persistent zinc-ion storage in mass-produced V2O5 architecture".NANO ENERGY 60(2019):171-178.
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