DICP OpenIR
Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters
Yang, Dong1,2; Su, Ming-zhi1,2; Zheng, Hui-jun1,2; Zhao, Zhi1; Li, Gang1; Kong, Xiang-tao1; Xie, Hua1; Fan, Hong-jun1; Zhang, Wei-qing1; Jiang, Ling1
Corresponding AuthorJiang, Ling(ljiang@dicp.ac.cn)
KeywordCationic cobalt Carbon dioxide Structure Infrared photodissociation spectroscopy Quantum chemical calculation
Source PublicationCHINESE JOURNAL OF CHEMICAL PHYSICS
2019-04-01
ISSN1674-0068
DOI10.1063/1674-0068/cjcp1902032
Volume32Issue:2Pages:223-228
Funding ProjectNational Natural Science Foundation of China[21327901] ; National Natural Science Foundation of China[21503222] ; National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation[2018M641718] ; China Postdoctoral Science Foundation[2018M641719]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordDRIVEN REDUCTIVE ACTIVATION ; CARBON-DIOXIDE ; ANIONIC COMPLEXES ; GROWTH DYNAMICS ; GAS ; SPECTRA ; SOLVATION ; LANTHANUM ; CHEMISTRY ; ATOMS
AbstractThe mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the interactions of cationic cobalt with carbon dioxide molecules. Quantum chemical calculations were performed on the [Co(CO2)(n)](+) clusters to identify the structures of the low-lying isomers and to assign the observed spectral features. All the [Co(CO2)(n)](+) (n=2-6) clusters studied here show resonances near the CO2 asymmetric stretch of free CO2 molecule. Experimental and calculated results indicate that the CO2 molecules are weakly bound to the Co+ cations in an end-on configuration via a charge-quadrupole electrostatic interaction. The present IRPD spectra of [Co(CO2)(n)](+) clusters have been compared to those of Ar-tagged species ([Co(CO2)(n)](+)-Ar), which would provide insights into the tagging effect of rare gas on the weakly-bounded clusters.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
WOS IDWOS:000467700000012
PublisherCHINESE PHYSICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171874
Collection中国科学院大连化学物理研究所
Corresponding AuthorJiang, Ling
Affiliation1.Chinese Acad Sci, State Key Lab Mol React Dynam, Collaborat Innovat Ctr Chem Energy & Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yang, Dong,Su, Ming-zhi,Zheng, Hui-jun,et al. Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2019,32(2):223-228.
APA Yang, Dong.,Su, Ming-zhi.,Zheng, Hui-jun.,Zhao, Zhi.,Li, Gang.,...&Jiang, Ling.(2019).Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters.CHINESE JOURNAL OF CHEMICAL PHYSICS,32(2),223-228.
MLA Yang, Dong,et al."Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters".CHINESE JOURNAL OF CHEMICAL PHYSICS 32.2(2019):223-228.
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