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Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization
Zhang, Yongliang1; Liu, Liang1; Chen, Tianyang1; Huang, Zhe1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,2
Corresponding AuthorZhang, Wen-Xiong(wx_zhang@pku.edu.cn) ; Xi, Zhenfeng(zfxi@pku.edu.cn)
Source PublicationORGANOMETALLICS
2019-05-13
ISSN0276-7333
DOI10.1021/acs.organomet.9b00154
Volume38Issue:9Pages:2174-2178
Funding ProjectNatural Science Foundation of China[21690061] ; Natural Science Foundation of China[21725201] ; Natural Science Foundation of China[21572005]
Funding OrganizationNatural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordELEMENTAL SULFUR ; INSERTION ; ZINCATION ; COMPLEX ; ETHERS ; BOND
AbstractIn this work, we report the synthesis and molecular structures of two kinds of organozinc metallacycles: dilithio spiro zincacyclopentadienes 3 and dizinca[10]cycles 4. Both complexes 3 and 4 were obtained from the reaction of 1,4-dilithio-1,3-butadienes 1 with ZnX2 (X = Cl, Br) in THF. The molecular structure of 3 was determined by single-crystal X-ray structural analysis and shows a spiro ring skeleton in which two zincacyclopentadienes are fused by a Zn(II) atom. Complex 3 represents the first well-defined examples of groups 12 metallacyclopentadienes. The molecular structure of 4 contains a distorted ten-membered dizincacycle. Multinuclear NMR measurements of 3 and 4 were conducted, and the structural transformations between them were observed. In addition, the insertion reaction of these organozinc metallacycles with S-8 or Se were investigated to give their corresponding thiophene or selenophene compounds.
Language英语
Funding OrganizationNatural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China
WOS IDWOS:000468120200035
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171884
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Wen-Xiong; Xi, Zhenfeng
Affiliation1.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, BNLMS,Minist Educ, Beijing 100871, Peoples R China
2.SIOC, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yongliang,Liu, Liang,Chen, Tianyang,et al. Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2019,38(9):2174-2178.
APA Zhang, Yongliang,Liu, Liang,Chen, Tianyang,Huang, Zhe,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2019).Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization.ORGANOMETALLICS,38(9),2174-2178.
MLA Zhang, Yongliang,et al."Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization".ORGANOMETALLICS 38.9(2019):2174-2178.
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