DICP OpenIR
Oxygen vacancy mediated La1-xCexFeO3-delta perovskite oxides as efficient catalysts for CWAO of acrylic acid by A-site Ce doping
Sun, Wenjing1,2; Wei, Huangzhao1; An, Lu Yang3; Jin, Chengyu1,2; Wu, Huiling1,2; Xiong, Zi-ang4; Pu, Chunying5; Sun, Chenglin1
Corresponding AuthorPu, Chunying(puchunying@126.com) ; Sun, Chenglin(clsun@dicp.ac.cn)
KeywordCatalytic wet air oxidation La1-xCexFeO3-delta Synergistic mechanism Generalized kinetic model First-principles calculations
Source PublicationAPPLIED CATALYSIS B-ENVIRONMENTAL
2019-05-15
ISSN0926-3373
DOI10.1016/j.apcatb.2018.12.024
Volume245Pages:20-28
Funding ProjectDICP[DICP ZZBS201614] ; Chinese Academy of Sciences[ZDRW-ZS-2016-5] ; National Natural Science Foundation of China[51878643]
Funding OrganizationDICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS SubjectChemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordWET AIR OXIDATION ; TOTAL-ENERGY CALCULATIONS ; AEROBIC OXIDATION ; AQUEOUS-SOLUTIONS ; LAFEO3 CATALYST ; LABO3 B ; PERFORMANCE ; CU ; DEGRADATION ; REMOVAL
AbstractThe influence of Ce amount on catalytic behaviour of perovskite catalysts La1-xCexFeO3-delta, prepared by coprecipitation was examined in catalytic wet air oxidation (CWAO) of high concentrated acrylic acid pollutant. The catalysts with the molar ratio of Ce/(La + Ce) upper than 0.4 exhibit high catalytic activity, and outstanding stability. Because Ce doping into the skeleton of LaFeO3 could cause the change of iron valence state as well as the change of the reactive oxygen species and oxygen vacancies of the catalyst. Three ways of O-2 involved in this reaction were considered, a synergistic mechanism of oxygen vacancies, the reversible electronic transition Fe3+ <-> Fe2+, and direct oxidization of acrylic acid. First-principles calculations revealed that the oxygen vacancy is more easily to form in the case of Ce content increasing in La1-xCexFeO3-delta, and oxygen would adsorb on oxygen vacancy to form reactive oxygen species. Consequently, the reactive oxygen species (O*) could oxidize acrylic acid. In this process, Fe ions of higher valence sate which would attack organic compounds and itself was reduced to Fe2+ to achieve catalytic cycles. Finally, the reaction was verified as first order, which was well explained by a proposed generalized kinetic model, in good accordance with our experimental data.
Language英语
Funding OrganizationDICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS IDWOS:000467661700003
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171914
Collection中国科学院大连化学物理研究所
Corresponding AuthorPu, Chunying; Sun, Chenglin
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Sinosteel Anshan Res Inst Thermoenergy Co Ltd, Natl Engn Res Ctr Coking Technol, Anshan 114044, Peoples R China
4.Dalian Univ Technol, Dalian 116024, Peoples R China
5.Nanyang Normal Univ, Coll Phys & Elect Engn, Nanyang 473061, Henan, Peoples R China
Recommended Citation
GB/T 7714
Sun, Wenjing,Wei, Huangzhao,An, Lu Yang,et al. Oxygen vacancy mediated La1-xCexFeO3-delta perovskite oxides as efficient catalysts for CWAO of acrylic acid by A-site Ce doping[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2019,245:20-28.
APA Sun, Wenjing.,Wei, Huangzhao.,An, Lu Yang.,Jin, Chengyu.,Wu, Huiling.,...&Sun, Chenglin.(2019).Oxygen vacancy mediated La1-xCexFeO3-delta perovskite oxides as efficient catalysts for CWAO of acrylic acid by A-site Ce doping.APPLIED CATALYSIS B-ENVIRONMENTAL,245,20-28.
MLA Sun, Wenjing,et al."Oxygen vacancy mediated La1-xCexFeO3-delta perovskite oxides as efficient catalysts for CWAO of acrylic acid by A-site Ce doping".APPLIED CATALYSIS B-ENVIRONMENTAL 245(2019):20-28.
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