DICP OpenIR
Synthesis of gasoline and jet fuel range cycloalkanes and aromatics from poly( ethylene terephthalate) waste
Tang, Hao1,2; Li, Ning1,3; Li, Guangyi1; Wang, Aiqin1; Cong, Yu1; Xu, Guotiang1; Wang, Xiaodong1; Zhang, Tao1,2
Corresponding AuthorLi, Ning(lining@dicp.ac.cn)
Source PublicationGREEN CHEMISTRY
2019-05-21
ISSN1463-9262
DOI10.1039/c9gc00571d
Volume21Issue:10Pages:2709-2719
Funding ProjectNational Natural Science Foundation of China[21690082] ; National Natural Science Foundation of China[21776273] ; National Natural Science Foundation of China[21721004] ; DNL Cooperation Fund, CAS[DNL180301] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA 21060200] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; Dalian Science Foundation for Distinguished Young Scholars[2015R005]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS Research AreaChemistry ; Science & Technology - Other Topics
WOS KeywordDIMETHYL TEREPHTHALATE ; RENEWABLE DIESEL ; CATALYSTS ; HYDROGENATION ; CONVERSION ; BIOMASS ; POLY(ETHYLENE-TEREPHTHALATE) ; HYDRODEOXYGENATION ; CHEMICALS ; METHANE
AbstractFor the first time, gasoline and jet fuel range C-7-C-8 cycloalkanes and aromatics were selectively synthesized by the alcoholysis of poly(ethylene terephthalate) (PET) waste, followed by solvent-free hydrogenation and hydrodeoxygenation (HDO). It was found that methanol is highly reactive for the alcoholysis of PET waste. In the absence of any catalyst, a high yield of dimethyl terephthalate (97.3%) was achieved under mild conditions (473 K, 3.5 h). Dimethyl terephthalate exists as a solid and can be automatically separated from methanol with a decrease in temperature. Subsequently, dimethyl terephthalate was liquefied to dimethyl cyclohexane-1,4-dicarboxylate by hydrogenation over noble metal catalysts. Among the investigated catalysts, Pt/C exhibited the highest activity. Finally, the dimethyl cyclohexane-1,4-dicarboxylate as obtained was further hydrodeoxygenated to C-7-C-8 cycloalkanes and aromatics that can be used as gasoline or additives to improve the densities (or volumetric heat value) and sealabilities of current bio-jet fuels. Bimetallic Ru-Cu/SiO2 was found to be a promising HDO catalyst. According to the characterization results, the excellent HDO performance of Ru-Cu/SiO2 can be explained by the formation of smaller Ru-Cu alloy particles during the catalyst preparation. In real applications, dimethyl cyclohexane-1,4-dicarboxylate can also be simultaneously hydrodeoxygenated with biomass derived oxygenates to produce jet fuel with a suitable content of cycloalkanes and aromatics.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars
WOS IDWOS:000468627800015
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/171922
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Ning
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
3.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Tang, Hao,Li, Ning,Li, Guangyi,et al. Synthesis of gasoline and jet fuel range cycloalkanes and aromatics from poly( ethylene terephthalate) waste[J]. GREEN CHEMISTRY,2019,21(10):2709-2719.
APA Tang, Hao.,Li, Ning.,Li, Guangyi.,Wang, Aiqin.,Cong, Yu.,...&Zhang, Tao.(2019).Synthesis of gasoline and jet fuel range cycloalkanes and aromatics from poly( ethylene terephthalate) waste.GREEN CHEMISTRY,21(10),2709-2719.
MLA Tang, Hao,et al."Synthesis of gasoline and jet fuel range cycloalkanes and aromatics from poly( ethylene terephthalate) waste".GREEN CHEMISTRY 21.10(2019):2709-2719.
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