DICP OpenIR
Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
Jia, Xiuquan1; Ma, Jiping1; Xia, Fei1,2; Gao, Mingxia1,2; Gao, Jin1; Xu, Jie1
Corresponding AuthorMa, Jiping(majiping@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
Source PublicationNATURE COMMUNICATIONS
2019-05-28
ISSN2041-1723
DOI10.1038/s41467-019-10315-9
Volume10Pages:7
Funding ProjectNational Natural Science Foundation of China[21703236] ; National Natural Science Foundation of China[21790331] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21030400] ; Youth Innovation Promotion Association, Chinese Academy of Sciences[2018219] ; DICP[ZZBS201811]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordAEROBIC OXIDATION ; CHEMOSELECTIVE HYDROGENATION ; REACTION PATHWAYS ; PRIMARY AMIDES ; NANOPARTICLES ; IMINES ; FUNCTIONALIZATION ; REACTIVITY ; ANCHORS ; COPPER
AbstractThe design of metal oxide catalysts predominantly focuses on the composition or geometry engineering to enable optimized reactivity on the surface. Despite the numerous reports investigating the surface chemisorption of organic molecules on metal oxides, insights into how adsorption of organic modifiers can be exploited to optimize the catalytic properties of metal oxides are lacking. Herein, we describe the use of enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide catalysts. The acetylacetone modification is stable under the reaction conditions and strongly influences the redox-acid cooperative catalysis of manganese oxides. This enables a rational control of the oxidation selectivity of structurally diverse arylmethyl amines to become switchable from nitriles to imines.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; DICP ; DICP
WOS IDWOS:000469221900002
PublisherNATURE PUBLISHING GROUP
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/172001
Collection中国科学院大连化学物理研究所
Corresponding AuthorMa, Jiping; Xu, Jie
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jia, Xiuquan,Ma, Jiping,Xia, Fei,et al. Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation[J]. NATURE COMMUNICATIONS,2019,10:7.
APA Jia, Xiuquan,Ma, Jiping,Xia, Fei,Gao, Mingxia,Gao, Jin,&Xu, Jie.(2019).Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation.NATURE COMMUNICATIONS,10,7.
MLA Jia, Xiuquan,et al."Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation".NATURE COMMUNICATIONS 10(2019):7.
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