DICP OpenIR
Two-dimensional materials for advanced Li-S batteries
Shao, Qinjun1,2; Wu, Zhong-Shuai3; Chen, Jian1
Corresponding AuthorChen, Jian(chenjian@dicp.ac.cn)
Source PublicationENERGY STORAGE MATERIALS
2019-11-01
ISSN2405-8297
DOI10.1016/j.ensm.2019.02.001
Volume22Pages:284-310
Funding ProjectStrategic Priority Research Program of Chinese Academy of Sciences[XDA09010303] ; National Key R&D Program of China[2016YFB0100100] ; DICP[DICP & QIBEBT UN201702] ; QIBEBT[DICP & QIBEBT UN201702]
Funding OrganizationStrategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS KeywordLITHIUM-SULFUR BATTERY ; REDUCED-GRAPHENE-OXIDE ; NITROGEN-DOPED GRAPHENE ; EFFICIENT POLYSULFIDE MEDIATOR ; METAL-ORGANIC FRAMEWORK ; HIGH-PERFORMANCE ; LONG-LIFE ; POROUS-GRAPHENE ; CARBON NANOSHEETS ; HOST MATERIALS
AbstractLithium-sulfur (Li-S) batteries are recognized as one of the most promising advanced energy storage systems due to high energy density, inexpensive and environmentally friendly elemental sulfur. However, the actual applications of Li-S batteries have been intrinsically plagued by capacity fading and low Coulombic efficiency mainly derived from the severe shuttle effect of lithium polysulfides (LiPSs). Recently, two-dimensional (2D) materials have been extensively explored to enhance the performance of Li-S batteries because of their unique 2D structure and diversified physicochemical properties. In this review, we summarized the state-of-the-art advances of 2D materials for advanced high-energy Li-S batteries. To specify their applications, we first overviewed various 2D materials (e.g. graphene, oxides, sulfides, carbides, nitrides) serving as insulating sulfur hosts with high surface area, excellent electrical conductivity and enriched functionality, to significantly buffer the volumetric variation and reduce the pulverization of the active sulfur, and boost the sulfur utilization and the improvement of cycle stability. Second, 2D materials with large lateral size, controllable interspaces, and enriched catalytic sites were good choices for separators and interlayers, which can efficiently prevent the diffusion and migration of the dissolved polysulfides via physical confinement and chemical interaction, revealing the synergistic effects for suppressing shuttle effect and stabilizing high performance. Besides, the 2D nanosheets-based interlayers and separators also contributed to prevent lithium anode from side reaction with LiPSs. Third, graphene and their analogues can act as the integrated interfacial layer and host of lithium metal, and effectively restrain the growth of lithium dendrite and guarantee the prolonged lithium stripping/ plating. Particular emphases are given to the unique structures, interfacial interactions, strategies for ingenious assembly and innovations of configuration in Li-S batteries. Finally, the remaining challenges and perspectives of Li-S batteries using 2D materials are briefly discussed.
Language英语
Funding OrganizationStrategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; DICP ; DICP ; QIBEBT ; QIBEBT
WOS IDWOS:000488256300030
PublisherELSEVIER
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/172426
Collection中国科学院大连化学物理研究所
Corresponding AuthorChen, Jian
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Adv Rechargeable Battery Lab, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Shao, Qinjun,Wu, Zhong-Shuai,Chen, Jian. Two-dimensional materials for advanced Li-S batteries[J]. ENERGY STORAGE MATERIALS,2019,22:284-310.
APA Shao, Qinjun,Wu, Zhong-Shuai,&Chen, Jian.(2019).Two-dimensional materials for advanced Li-S batteries.ENERGY STORAGE MATERIALS,22,284-310.
MLA Shao, Qinjun,et al."Two-dimensional materials for advanced Li-S batteries".ENERGY STORAGE MATERIALS 22(2019):284-310.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Shao, Qinjun]'s Articles
[Wu, Zhong-Shuai]'s Articles
[Chen, Jian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Shao, Qinjun]'s Articles
[Wu, Zhong-Shuai]'s Articles
[Chen, Jian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Shao, Qinjun]'s Articles
[Wu, Zhong-Shuai]'s Articles
[Chen, Jian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.